Orientation in molecule-surface interactions

Heinzmann U, Holloway S, Kleyn AW, Palmer RE, Snowdon KJ (1996)
JOURNAL OF PHYSICS-CONDENSED MATTER 8(19): 3245-3269.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The role of the orientation of a molecule in its interaction with a surface is examined for a number of cases. At first the determination of the static orientation of a molecule at the surface is discussed. A dependence of the orientation on state and coverage is found for O-2 molecules adsorbed on Ag(110). The orientation dependence of NO in chemisorption, displacement reactions, and chemical reactions is discussed. Rotational excitation of NO in collisions with surfaces is shown to exhibit a strong orientation dependence. Dissociative chemisorption of hydrogen molecules is found to depend on the initial orientation of the molecule. Finally, in dissociative collisions of fast molecules with surfaces the role of the initial orientation is examined and the final orientation of the molecular axis is determined. Several mechanisms for molecular dissociation are discussed.
Erscheinungsjahr
Zeitschriftentitel
JOURNAL OF PHYSICS-CONDENSED MATTER
Band
8
Zeitschriftennummer
19
Seite
3245-3269
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eISSN
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Heinzmann U, Holloway S, Kleyn AW, Palmer RE, Snowdon KJ. Orientation in molecule-surface interactions. JOURNAL OF PHYSICS-CONDENSED MATTER. 1996;8(19):3245-3269.
Heinzmann, U., Holloway, S., Kleyn, A. W., Palmer, R. E., & Snowdon, K. J. (1996). Orientation in molecule-surface interactions. JOURNAL OF PHYSICS-CONDENSED MATTER, 8(19), 3245-3269. doi:10.1088/0953-8984/8/19/002
Heinzmann, U., Holloway, S., Kleyn, A. W., Palmer, R. E., and Snowdon, K. J. (1996). Orientation in molecule-surface interactions. JOURNAL OF PHYSICS-CONDENSED MATTER 8, 3245-3269.
Heinzmann, U., et al., 1996. Orientation in molecule-surface interactions. JOURNAL OF PHYSICS-CONDENSED MATTER, 8(19), p 3245-3269.
U. Heinzmann, et al., “Orientation in molecule-surface interactions”, JOURNAL OF PHYSICS-CONDENSED MATTER, vol. 8, 1996, pp. 3245-3269.
Heinzmann, U., Holloway, S., Kleyn, A.W., Palmer, R.E., Snowdon, K.J.: Orientation in molecule-surface interactions. JOURNAL OF PHYSICS-CONDENSED MATTER. 8, 3245-3269 (1996).
Heinzmann, Ulrich, Holloway, S, Kleyn, AW, Palmer, RE, and Snowdon, KJ. “Orientation in molecule-surface interactions”. JOURNAL OF PHYSICS-CONDENSED MATTER 8.19 (1996): 3245-3269.