The phospha-2-allyl-system: Electrochemical and quantum chemical investigations

Schoeller W, Haug W, Strutwolf J, Busch T (1996)
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 92(10): 1751-1755.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Electrochemical investigations on some substituted phospha-2-allyl cations are performed. The phospha-2-allyl cation prefers a bent rather than a linear allene-type structure. According to quantum chemical calculations, in the lowest energy doublet state the single electron resides in the non-bonding orbital of the pi-system. The electrochemical investigations on some substituted substrates indicate irreversible oxidation to the radical dication as well as one-electron and two-electron reduction to the radical and anion. The various substituent effects as well as the electronic properties of the parent cation, radical and anion and its valence isomers are rationalized by quantum chemical calculations.
Erscheinungsjahr
Zeitschriftentitel
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
Band
92
Zeitschriftennummer
10
Seite
1751-1755
ISSN
eISSN
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Schoeller W, Haug W, Strutwolf J, Busch T. The phospha-2-allyl-system: Electrochemical and quantum chemical investigations. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS. 1996;92(10):1751-1755.
Schoeller, W., Haug, W., Strutwolf, J., & Busch, T. (1996). The phospha-2-allyl-system: Electrochemical and quantum chemical investigations. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 92(10), 1751-1755. doi:10.1039/ft9969201751
Schoeller, W., Haug, W., Strutwolf, J., and Busch, T. (1996). The phospha-2-allyl-system: Electrochemical and quantum chemical investigations. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 92, 1751-1755.
Schoeller, W., et al., 1996. The phospha-2-allyl-system: Electrochemical and quantum chemical investigations. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 92(10), p 1751-1755.
W. Schoeller, et al., “The phospha-2-allyl-system: Electrochemical and quantum chemical investigations”, JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, vol. 92, 1996, pp. 1751-1755.
Schoeller, W., Haug, W., Strutwolf, J., Busch, T.: The phospha-2-allyl-system: Electrochemical and quantum chemical investigations. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS. 92, 1751-1755 (1996).
Schoeller, Wolfgang, Haug, W, Strutwolf, J, and Busch, T. “The phospha-2-allyl-system: Electrochemical and quantum chemical investigations”. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 92.10 (1996): 1751-1755.