(Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate

Jutzi P, Strassburger G, Schneider M, Stammler H-G, Neumann B (1996)
ORGANOMETALLICS 15(12): 2842-2844.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Hydrolysis of Cp*SiCl3 affords the silanetriol Cp*Si(OH)(3) (1) as an amorphous solid. Reaction of 1 with Me(3)SiCl/NEt(3) and with N(SnMe(3))(3) leads to Cp*Si(OSiMe(3))(3) (2) and Cp*Si(OSnMe(3))(3) (3), respectively. From a concentrated solution of 1 in diethyl ether, the hemihydrate Cp*Si(OH)(3) . 0.5 H2O (4) is obtained as colorless crystals. An X-ray crystal structure analysis of 4 reveals that Cp*Si(OH)(3) and water molecules are hydrogen-bonded to form a multilayer arrangement with the pentamethylcyclopentadienyl groups forming the hydrophobic outer sheets and the silanetriol groups together with the water molecules forming the hydrophilic inner sheets.
Erscheinungsjahr
Zeitschriftentitel
ORGANOMETALLICS
Band
15
Zeitschriftennummer
12
Seite
2842-2844
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Jutzi P, Strassburger G, Schneider M, Stammler H-G, Neumann B. (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS. 1996;15(12):2842-2844.
Jutzi, P., Strassburger, G., Schneider, M., Stammler, H. - G., & Neumann, B. (1996). (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS, 15(12), 2842-2844. doi:10.1021/om9509756
Jutzi, P., Strassburger, G., Schneider, M., Stammler, H. - G., and Neumann, B. (1996). (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS 15, 2842-2844.
Jutzi, P., et al., 1996. (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS, 15(12), p 2842-2844.
P. Jutzi, et al., “(Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate”, ORGANOMETALLICS, vol. 15, 1996, pp. 2842-2844.
Jutzi, P., Strassburger, G., Schneider, M., Stammler, H.-G., Neumann, B.: (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS. 15, 2842-2844 (1996).
Jutzi, Peter, Strassburger, G, Schneider, M, Stammler, Hans-Georg, and Neumann, B. “(Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate”. ORGANOMETALLICS 15.12 (1996): 2842-2844.