(Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate

Jutzi P, Strassburger G, Schneider M, Stammler H-G, Neumann B (1996)
ORGANOMETALLICS 15(12): 2842-2844.

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Abstract
Hydrolysis of Cp*SiCl3 affords the silanetriol Cp*Si(OH)(3) (1) as an amorphous solid. Reaction of 1 with Me(3)SiCl/NEt(3) and with N(SnMe(3))(3) leads to Cp*Si(OSiMe(3))(3) (2) and Cp*Si(OSnMe(3))(3) (3), respectively. From a concentrated solution of 1 in diethyl ether, the hemihydrate Cp*Si(OH)(3) . 0.5 H2O (4) is obtained as colorless crystals. An X-ray crystal structure analysis of 4 reveals that Cp*Si(OH)(3) and water molecules are hydrogen-bonded to form a multilayer arrangement with the pentamethylcyclopentadienyl groups forming the hydrophobic outer sheets and the silanetriol groups together with the water molecules forming the hydrophilic inner sheets.
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Jutzi P, Strassburger G, Schneider M, Stammler H-G, Neumann B. (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS. 1996;15(12):2842-2844.
Jutzi, P., Strassburger, G., Schneider, M., Stammler, H. - G., & Neumann, B. (1996). (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS, 15(12), 2842-2844.
Jutzi, P., Strassburger, G., Schneider, M., Stammler, H. - G., and Neumann, B. (1996). (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS 15, 2842-2844.
Jutzi, P., et al., 1996. (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS, 15(12), p 2842-2844.
P. Jutzi, et al., “(Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate”, ORGANOMETALLICS, vol. 15, 1996, pp. 2842-2844.
Jutzi, P., Strassburger, G., Schneider, M., Stammler, H.-G., Neumann, B.: (Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate. ORGANOMETALLICS. 15, 2842-2844 (1996).
Jutzi, Peter, Strassburger, G, Schneider, M, Stammler, Hans-Georg, and Neumann, B. “(Pentamethylcyclopentadienyl)silanetriol: Synthesis, derivatization, and X-ray crystal structure of its hemihydrate”. ORGANOMETALLICS 15.12 (1996): 2842-2844.
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