Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O

Plass W, Müller A, Krickemeyer E, Bögge H, Diemann E (1996)
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE 133(3): 225-227.

Journal Article | Published | English

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Abstract
Reaction of iron(III) acetylacetonate with K2CS3 in DMF and precipitation with [PPh(4)]Cl gives [PPh(4)](3)[Fe(CS3)(3)]. H2O, the crystal structure of which shows octahedrally-coordinated iron centers within the discrete [Fe(CS3)(3)](3-) anions with interesting electronic structure. The CS32- group acts as a bidentate ligand with resulting FeS distances ranging from 2.286 to 2.323 Angstrom.
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Plass W, Müller A, Krickemeyer E, Bögge H, Diemann E. Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE. 1996;133(3):225-227.
Plass, W., Müller, A., Krickemeyer, E., Bögge, H., & Diemann, E. (1996). Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 133(3), 225-227.
Plass, W., Müller, A., Krickemeyer, E., Bögge, H., and Diemann, E. (1996). Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE 133, 225-227.
Plass, W., et al., 1996. Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 133(3), p 225-227.
W. Plass, et al., “Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O”, BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, vol. 133, 1996, pp. 225-227.
Plass, W., Müller, A., Krickemeyer, E., Bögge, H., Diemann, E.: Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE. 133, 225-227 (1996).
Plass, W, Müller, Achim, Krickemeyer, Erich, Bögge, Hartmut, and Diemann, Ekkehard. “Synthesis and electronic structure of a homoleptic trithiocarbonato iron complex: [PPh(4)](3)[Fe(CS3)(3)]center dot H2O”. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE 133.3 (1996): 225-227.
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