Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe

Müller A, Johannes KU, Plass W, Bögge H, Krahn E, Schneider K (1996)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 622(10): 1765-1772.

Journal Article | Published | German

No fulltext has been uploaded

Author
; ; ; ; ;
Alternative Title
Green bis-(2-iminoisopropyl-thiophenolato)nickel(II) and other similar Ni-II complexes
Abstract
The compounds [Ni-II(iitp)(2)] 1 (iitp=2-iminoisopropyl-thiophenolate), [Ni-2(II)(imptp)(2)]. 2CH(3)OH 2, a dinuclear compound with an Ni-Ni distance of 276 pm, and [PPh(4)].[Ni-II(imptp)(SCN)] 3 (imptp=2-(2-iminopentane-4-on)-thiophenolate) have been prepared by the reaction of nickel(II)-acetate-tetrahydrate with 2-iminoisopropyl-thiophenole and 2-(2-iminopentane-4-on)-thiophenole in methanol, respectively. They have been characterized by single-crystal X-ray structure analysis and other physical methods. The redox behaviour of 1-3 has been studied in detail (chemically as well as by cyclovoltammetry and ESR spectroscopy). Particularly interesting are the electronic properties of 1 and its reduction with NaBH4 and the following reaction of the product with O-2 The complexes are model compounds for some Ni-containing enzymes. For details of the crystal structure determination see ''Inhaltsubersicht''.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Müller A, Johannes KU, Plass W, Bögge H, Krahn E, Schneider K. Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 1996;622(10):1765-1772.
Müller, A., Johannes, K. U., Plass, W., Bögge, H., Krahn, E., & Schneider, K. (1996). Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 622(10), 1765-1772.
Müller, A., Johannes, K. U., Plass, W., Bögge, H., Krahn, E., and Schneider, K. (1996). Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 622, 1765-1772.
Müller, A., et al., 1996. Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 622(10), p 1765-1772.
A. Müller, et al., “Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 622, 1996, pp. 1765-1772.
Müller, A., Johannes, K.U., Plass, W., Bögge, H., Krahn, E., Schneider, K.: Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 622, 1765-1772 (1996).
Müller, Achim, Johannes, KU, Plass, W, Bögge, Hartmut, Krahn, E, and Schneider, Klaus. “Über grünes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ähnliche NiII-Komplexe”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 622.10 (1996): 1765-1772.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar