Photocyclizable resorcin[4]arene dimers

Schäfer C, Strübe F, Bringmann S, Mattay J (2008)
Photochemical & Photobiological Sciences 7(12): 1457-1462.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
The synthesis of covalently linked dimers, containing two resorcin[ 4] arene moieties connected over two 9,10-functionalized anthracene units, is reported. Besides the synthetic route, which involves for example the formation of anthracene-9,10-dialkanols ( 4 and 5), and characterization of the compounds, the photochemical properties, introduced through the anthracene groups, were investigated by means of UV/VIS spectroscopy. Both resorcin[ 4] arene dimers ( 1 and 2) were able to undergo an intramolecular [ 4 + 4] cycloaddition, therefore changing the size of the inner cavity. Unfortunately, the back reaction, which was expected to take place on irradiation below 300 nm or upon heating, was not observed yet and will be the focus of our future work.
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Zeitschriftentitel
Photochemical & Photobiological Sciences
Band
7
Ausgabe
12
Seite(n)
1457-1462
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Schäfer C, Strübe F, Bringmann S, Mattay J. Photocyclizable resorcin[4]arene dimers. Photochemical & Photobiological Sciences. 2008;7(12):1457-1462.
Schäfer, C., Strübe, F., Bringmann, S., & Mattay, J. (2008). Photocyclizable resorcin[4]arene dimers. Photochemical & Photobiological Sciences, 7(12), 1457-1462. doi:10.1039/b807700b
Schäfer, C., Strübe, F., Bringmann, S., and Mattay, J. (2008). Photocyclizable resorcin[4]arene dimers. Photochemical & Photobiological Sciences 7, 1457-1462.
Schäfer, C., et al., 2008. Photocyclizable resorcin[4]arene dimers. Photochemical & Photobiological Sciences, 7(12), p 1457-1462.
C. Schäfer, et al., “Photocyclizable resorcin[4]arene dimers”, Photochemical & Photobiological Sciences, vol. 7, 2008, pp. 1457-1462.
Schäfer, C., Strübe, F., Bringmann, S., Mattay, J.: Photocyclizable resorcin[4]arene dimers. Photochemical & Photobiological Sciences. 7, 1457-1462 (2008).
Schäfer, Christian, Strübe, Frank, Bringmann, Sebastian, and Mattay, Jochen. “Photocyclizable resorcin[4]arene dimers”. Photochemical & Photobiological Sciences 7.12 (2008): 1457-1462.

4 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Light-responsive molecular containers.
Díaz-Moscoso A, Ballester P., Chem Commun (Camb) 53(34), 2017
PMID: 28382335
Anthracene photodimerization in a bis-chromophoric hydrogen-bonding receptor.
Liang CK, Desvergne JP, Bassani DM., Photochem Photobiol Sci 13(2), 2014
PMID: 24276577
Anthracene-resorcin[4]arene-based capsules: synthesis and photoswitchable features.
Bringmann S, Brodbeck R, Hartmann R, Schäfer C, Mattay J., Org Biomol Chem 9(21), 2011
PMID: 21927749

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