Rare-earth metal hydroxylamide complexes

Venugopal A, Hepp A, Pape T, Mix A, Mitzel NW (2008)
DALTON TRANSACTIONS (46): 6628-6633.

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Abstract
The rare-earth metal hydroxylamide compound Y[N(SiHMe2)(2)](2)[ONBn2][THF] (1) was prepared by the silylamide elimination pathway from the reaction of N, N-dibenzylhydroxylamine, Bn2NOH (Bn = CH2C6H5), with Y[ N(SiHMe2)(2)](3)[THF](2) and was characterised by multinuclear NMR spectroscopy and elemental analysis. The compounds [Cp2Y(ONBn2)](2) (2a) [Cp2Sm(ONBn2)](2) (2b) were obtained by the reactions of MCp3 (M = Y, Sm) with Bn2NOH. The trinuclear compound Cp5Y3[ON(Me)CH2CH2(Me)NO](2) (3) was obtained by the reaction of YCp3 and the bishydroxylamine HON(Me)CH2CH2(Me)NOH. 2a, 2b and 3 were characterised by NMR spectroscopy, single-crystal X-ray diffraction and elemental analysis. In all these complexes side-on-coordination of the hydroxylamide units was observed. The compounds are of dynamic nature in solution.
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Venugopal A, Hepp A, Pape T, Mix A, Mitzel NW. Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS. 2008;(46):6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., & Mitzel, N. W. (2008). Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS(46), 6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., and Mitzel, N. W. (2008). Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS, 6628-6633.
Venugopal, A., et al., 2008. Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS, (46), p 6628-6633.
A. Venugopal, et al., “Rare-earth metal hydroxylamide complexes”, DALTON TRANSACTIONS, 2008, pp. 6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., Mitzel, N.W.: Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS. 6628-6633 (2008).
Venugopal, Ajay, Hepp, Alexander, Pape, Tania, Mix, Andreas, and Mitzel, Norbert W. “Rare-earth metal hydroxylamide complexes”. DALTON TRANSACTIONS 46 (2008): 6628-6633.
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Trinuclear pyridyl functionalised hydroxylaminato complexes of aluminium, gallium and indium.
Hellmann BJ, Mix A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 39(30), 2010
PMID: 20577701

23 References

Data provided by Europe PubMed Central.


mitzel, j chem soc dalton trans (), 1996

ullrich, eur j inorg chem (), 2004

herrmann, z naturforsch b chem sci 49(), 1994
Der hoch flexible Bis(hydroxylamin)-Ligand [ON(Me)]2CH22− und sein unterschiedliches Verhalten in der Chemie des Aluminiums und Galliums
Lustig, Angewandte Chemie 113(23), 2001
Electrochemical reduction of dialkylamide and bis-trimethylsilylamido complexes of chromium(III) and ytterbium in non-aqueous solvents
Bradley, Polyhedron 2(2), 1983
Mono(cyclopentadienyl) complexes of the rare-earth metals.
Arndt S, Okuda J., Chem. Rev. 102(6), 2002
PMID: 12059259
Synthesis and structural characterisation of rare-earth bis(dimethylsilyl)amides and their surface organometallic chemistry on mesoporous MCM-41 †
Anwander, Journal of the Chemical Society Dalton Transactions (5), 1998
A diphenylboron chelate of an ethylenebishydroxylamine formaldehyde adduct
Kliegel, Acta Crystallographica Section E Structure Reports Online 58(5), 2002
Different modes of aggregation in organoaluminium and -gallium hydroxylamides.
Mitzel NW, Lustig C, Woski M., Dalton Trans (3), 2004
PMID: 15252545
Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides
Bradley, Journal of the Chemical Society Dalton Transactions (10), 1973
Hydroxylamido(1-)-Komplexe des Titan(IV) und Zirkonium(IV) Die Kristall- und Molekülstruktur von Tetrakis-(N,N-diethylhydroxylamido(1-)-O,N)titan(IV)
Wieghardt, Zeitschrift für anorganische und allgemeine Chemie 490(1), 1982

Birmingham, Journal of the American Chemical Society 78(1), 1956
Reactions of d0 group 4 amides with dioxygen. Preparation of unusual oxo aminoxy complexes and theoretical studies of their formation.
Wang R, Zhang XH, Chen SJ, Yu X, Wang CS, Beach DB, Wu YD, Xue ZL., J. Am. Chem. Soc. 127(14), 2005
PMID: 15810856
Ln(AlMe4)3 as New Synthetic Precursors in Organolanthanide Chemistry: Efficient Access to Half-Sandwich Hydrocarbyl Complexes
Dietrich, Organometallics 24(23), 2005
First mixed hydrazide/hydroxylamide metal aggregates.
Jana S, Berger RJ, Frohlich R, Mitzel NW., Chem. Commun. (Camb.) (38), 2006
PMID: 17003876
Homoleptic 12-coordinate lanthanoids with eta(2)-nitroso ligands.
Chesman AS, Turner DR, Izgorodina EI, Batten SR, Deacon GB., Dalton Trans (14), 2007
PMID: 17387395
Bis(phosphinimino)methanide Rare Earth Amides: Synthesis, Structure, and Catalysis of Hydroamination/Cyclization, Hydrosilylation, and Sequential Hydroamination/Hydrosilylation
Rastätter, Chemistry - A European Journal 13(13), 2007
Hydroxylaminato yttrate and samarate complexes.
Venugopal A, Willner A, Hepp A, Mitzel NW., Dalton Trans (29), 2007
PMID: 17637986
Structural diversity in bishydroxylamine complexes of gallium.
Bosing P, Willner A, Pape T, Hepp A, Mitzel NW., Dalton Trans (19), 2008
PMID: 18443697

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