Synthesis of terpyridine-substituted calix[n]arenes

Liu J, Tonigold M, Bredenkoetter B, Schröder T, Mattay J, Volkmer D (2009)
TETRAHEDRON LETTERS 50(12): 1303-1306.

Journal Article | Published | English

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Abstract
Calix[n]arenes (n = 4,5) comprising 4-(2,2':6',2 ''-terpyridyl)-phenyl substituents at the upper rim were synthesized for the first time, employing Suzuki-type coupling reactions. All calix[n]arene derivatives were prepared as cone conformers. The single crystal X-ray structure of cone-5,11,17,23-tetra{4-(2,2':6',2 ''-terpyridyl)-phenyl)-25,26,27,28-tetrabutoxycalix[4]arene 4 is analyzed in terms Of Structural rigidity and potential use of these ligands as novel synthons of cage-type metallosupramolecular assemblies. (C) 2009 Elsevier Ltd. All rights reserved.
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Liu J, Tonigold M, Bredenkoetter B, Schröder T, Mattay J, Volkmer D. Synthesis of terpyridine-substituted calix[n]arenes. TETRAHEDRON LETTERS. 2009;50(12):1303-1306.
Liu, J., Tonigold, M., Bredenkoetter, B., Schröder, T., Mattay, J., & Volkmer, D. (2009). Synthesis of terpyridine-substituted calix[n]arenes. TETRAHEDRON LETTERS, 50(12), 1303-1306.
Liu, J., Tonigold, M., Bredenkoetter, B., Schröder, T., Mattay, J., and Volkmer, D. (2009). Synthesis of terpyridine-substituted calix[n]arenes. TETRAHEDRON LETTERS 50, 1303-1306.
Liu, J., et al., 2009. Synthesis of terpyridine-substituted calix[n]arenes. TETRAHEDRON LETTERS, 50(12), p 1303-1306.
J. Liu, et al., “Synthesis of terpyridine-substituted calix[n]arenes”, TETRAHEDRON LETTERS, vol. 50, 2009, pp. 1303-1306.
Liu, J., Tonigold, M., Bredenkoetter, B., Schröder, T., Mattay, J., Volkmer, D.: Synthesis of terpyridine-substituted calix[n]arenes. TETRAHEDRON LETTERS. 50, 1303-1306 (2009).
Liu, Junmin, Tonigold, Markus, Bredenkoetter, Bjoern, Schröder, Tobias, Mattay, Jochen, and Volkmer, Dirk. “Synthesis of terpyridine-substituted calix[n]arenes”. TETRAHEDRON LETTERS 50.12 (2009): 1303-1306.
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