Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound

Jutzi P, Leszczynska K, Mix A, Neumann B, Schoeller W, Stammler H-G (2009)
ORGANOMETALLICS 28(7): 1985-1987.

Journal Article | Published | English

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Reaction of the Cp*Si+ cation with the beta-diketiminato anion [HC(CMeNAryl)(2)](-) (Aryl=2,6-iPr(2)C(6)H(3)) did not lead to the expected silicon(II) compound Cp*[HC(CMeNAryl)(2)]Si (3) but to the constitutional isomer 7 containing a silicon(IV) center. Calculations were performed for 3, for the conformational isomer 3* containing a eta(3)-Cp* ligand, and for less substituted species.
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Jutzi P, Leszczynska K, Mix A, Neumann B, Schoeller W, Stammler H-G. Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound. ORGANOMETALLICS. 2009;28(7):1985-1987.
Jutzi, P., Leszczynska, K., Mix, A., Neumann, B., Schoeller, W., & Stammler, H. - G. (2009). Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound. ORGANOMETALLICS, 28(7), 1985-1987.
Jutzi, P., Leszczynska, K., Mix, A., Neumann, B., Schoeller, W., and Stammler, H. - G. (2009). Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound. ORGANOMETALLICS 28, 1985-1987.
Jutzi, P., et al., 2009. Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound. ORGANOMETALLICS, 28(7), p 1985-1987.
P. Jutzi, et al., “Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound”, ORGANOMETALLICS, vol. 28, 2009, pp. 1985-1987.
Jutzi, P., Leszczynska, K., Mix, A., Neumann, B., Schoeller, W., Stammler, H.-G.: Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound. ORGANOMETALLICS. 28, 1985-1987 (2009).
Jutzi, Peter, Leszczynska, Kinga, Mix, Andreas, Neumann, Beate, Schoeller, Wolfgang, and Stammler, Hans-Georg. “Reaction of the (Pentamethylcyclopentadienyl)silicon(II) Cation with a Sterically Encumbered beta-Diketiminato Anion: Unexpected Formation of a Tricyclic Silicon(IV) Compound”. ORGANOMETALLICS 28.7 (2009): 1985-1987.
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