Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W)

Todea AM, Merca A, Bögge H, Glaser T, Engelhardt L, Prozorov R, Lubanc M, Müller A (2009)
Chemical Communications (23): 3351-3353.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The deliberate synthesis of the Keplerate [K-20 subset of {(W)W5O21(SO4)}(12)(VO)(30)(SO4)(H2O)(63)](18-) 1a with 20 pores all closed by K+ in a supramolecular fashion proves that it is possible to follow new routes in polyoxotungstate chemistry based on pentagonal {(W)W-5}-type units and to tune magnetic exchange couplings in {(M)M-5}(12)M'(30) type Keplerates.
Erscheinungsjahr
Zeitschriftentitel
Chemical Communications
Zeitschriftennummer
23
Seite
3351-3353
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Todea AM, Merca A, Bögge H, et al. Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications. 2009;(23):3351-3353.
Todea, A. M., Merca, A., Bögge, H., Glaser, T., Engelhardt, L., Prozorov, R., Lubanc, M., et al. (2009). Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications(23), 3351-3353. doi:10.1039/b907188a
Todea, A. M., Merca, A., Bögge, H., Glaser, T., Engelhardt, L., Prozorov, R., Lubanc, M., and Müller, A. (2009). Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications, 3351-3353.
Todea, A.M., et al., 2009. Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications, (23), p 3351-3353.
A.M. Todea, et al., “Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W)”, Chemical Communications, 2009, pp. 3351-3353.
Todea, A.M., Merca, A., Bögge, H., Glaser, T., Engelhardt, L., Prozorov, R., Lubanc, M., Müller, A.: Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications. 3351-3353 (2009).
Todea, Ana Maria, Merca, Alice, Bögge, Hartmut, Glaser, Thorsten, Engelhardt, Larry, Prozorov, Ruslan, Lubanc, Marshall, and Müller, Achim. “Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W)”. Chemical Communications 23 (2009): 3351-3353.

6 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Assembly of Tungsten-Oxide-Based Pentagonal Motifs in Solution Leads to Nanoscale {W48}, {W56}, and {W92} Polyoxometalate Clusters.
Zhan CH, Winter RS, Zheng Q, Yan J, Cameron JM, Long DL, Cronin L., Angew Chem Int Ed Engl 54(48), 2015
PMID: 26449850
Picking up 30 CO2 molecules by a porous metal oxide capsule based on the same number of receptors.
Garai S, Haupt ET, Bögge H, Merca A, Müller A., Angew Chem Int Ed Engl 51(42), 2012
PMID: 23001843
Molecular growth of a core-shell polyoxometalate.
Fang X, Kögerler P, Furukawa Y, Speldrich M, Luban M., Angew Chem Int Ed Engl 50(22), 2011
PMID: 21506214
Softening of pore and interior properties of a metal-oxide-based capsule: substituting 60 oxide by 60 sulfide ligands.
Schäffer C, Todea AM, Bögge H, Cadot E, Gouzerh P, Kopilevich S, Weinstock IA, Müller A., Angew Chem Int Ed Engl 50(51), 2011
PMID: 22034074
Electronic control of spin coupling in keplerate-type polyoxomolybdates.
Botar B, Ellern A, Hermann R, Kögerler P., Angew Chem Int Ed Engl 48(48), 2009
PMID: 19859930

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