Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W)

Todea AM, Merca A, Bögge H, Glaser T, Engelhardt L, Prozorov R, Lubanc M, Müller A (2009)
Chemical Communications (23): 3351-3353.

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The deliberate synthesis of the Keplerate [K-20 subset of {(W)W5O21(SO4)}(12)(VO)(30)(SO4)(H2O)(63)](18-) 1a with 20 pores all closed by K+ in a supramolecular fashion proves that it is possible to follow new routes in polyoxotungstate chemistry based on pentagonal {(W)W-5}-type units and to tune magnetic exchange couplings in {(M)M-5}(12)M'(30) type Keplerates.
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Todea AM, Merca A, Bögge H, et al. Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications. 2009;(23):3351-3353.
Todea, A. M., Merca, A., Bögge, H., Glaser, T., Engelhardt, L., Prozorov, R., Lubanc, M., et al. (2009). Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications(23), 3351-3353. doi:10.1039/b907188a
Todea, A. M., Merca, A., Bögge, H., Glaser, T., Engelhardt, L., Prozorov, R., Lubanc, M., and Müller, A. (2009). Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications, 3351-3353.
Todea, A.M., et al., 2009. Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications, (23), p 3351-3353.
A.M. Todea, et al., “Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W)”, Chemical Communications, 2009, pp. 3351-3353.
Todea, A.M., Merca, A., Bögge, H., Glaser, T., Engelhardt, L., Prozorov, R., Lubanc, M., Müller, A.: Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W). Chemical Communications. 3351-3353 (2009).
Todea, Ana Maria, Merca, Alice, Bögge, Hartmut, Glaser, Thorsten, Engelhardt, Larry, Prozorov, Ruslan, Lubanc, Marshall, and Müller, Achim. “Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M-5}(12)V-30 Keplerates (M = Mo, W)”. Chemical Communications 23 (2009): 3351-3353.
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6 Citations in Europe PMC

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Assembly of Tungsten-Oxide-Based Pentagonal Motifs in Solution Leads to Nanoscale {W48}, {W56}, and {W92} Polyoxometalate Clusters.
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Garai S, Haupt ET, Bögge H, Merca A, Müller A., Angew Chem Int Ed Engl 51(42), 2012
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Fang X, Kögerler P, Furukawa Y, Speldrich M, Luban M., Angew Chem Int Ed Engl 50(22), 2011
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Softening of pore and interior properties of a metal-oxide-based capsule: substituting 60 oxide by 60 sulfide ligands.
Schäffer C, Todea AM, Bögge H, Cadot E, Gouzerh P, Kopilevich S, Weinstock IA, Müller A., Angew Chem Int Ed Engl 50(51), 2011
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Electronic control of spin coupling in keplerate-type polyoxomolybdates.
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