Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles)

Weber L (2008)
Coordination Chemistry Reviews 252(1-2): 1-31.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
1,3,2-Diazaborolines(2,3-dihydro-1H-1,3,2-diazaboroles) are compounds at the interface between inorganic, organometallic and organic chemistry. The planar rings with 6 pi-electrons may be regarded as heteroarenes, as evident by NMR and photoelectron spectra and confirmed by quantum chemical studies. High-yield syntheses of functionalized 1,3,2-diazaborolines have been elaborated, providing a prolific area of chemistry. Conjugation of the vacant 2p(z)-orbital on the boron center with the pi* orbital of attached organic pi-systems proved to be responsible for unique absorption and emission characteristics of 1,3,2-diazaborolinyl functionalized biphenyls, thiophenes and dithiophenes. Most of the functionalized diazaborolines show clean irreversible oxidation waves in their cyclovoltammograms. (C) 2007 Elsevier B.V. All rights reserved.
Erscheinungsjahr
Zeitschriftentitel
Coordination Chemistry Reviews
Band
252
Zeitschriftennummer
1-2
Seite
1-31
ISSN
PUB-ID

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Weber L. Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews. 2008;252(1-2):1-31.
Weber, L. (2008). Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews, 252(1-2), 1-31. doi:10.1016/j.ccr.2007.02.014
Weber, L. (2008). Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews 252, 1-31.
Weber, L., 2008. Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews, 252(1-2), p 1-31.
L. Weber, “Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles)”, Coordination Chemistry Reviews, vol. 252, 2008, pp. 1-31.
Weber, L.: Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews. 252, 1-31 (2008).
Weber, Lothar. “Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles)”. Coordination Chemistry Reviews 252.1-2 (2008): 1-31.