ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY

FUCHS E, BREIT B, HEYDT H, Schoeller W, BUSCH T, KRUGER C, BETZ P, REGITZ M (1991)
CHEMISCHE BERICHTE-RECUEIL 124(12): 2843-2855.

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Abstract
Peterson olefination of the sterically hindered cyclopropenones 1 with the lithium phosphides 2 yields the so far unknown phophatriafulvenes 3 and 4, which possess inverse electron densities. They are characterized by transition metal complex formation (--> 7, 8). Acylation of 3a with the carboxylic acid chlorides 11 leads to a great variety of P-acylphosphatriafulvenes 13a-s. They partly dimerize under formation of the 1,3-diphosphacyclobutanes 13 reversible 14.
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FUCHS E, BREIT B, HEYDT H, et al. ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY. CHEMISCHE BERICHTE-RECUEIL. 1991;124(12):2843-2855.
FUCHS, E., BREIT, B., HEYDT, H., Schoeller, W., BUSCH, T., KRUGER, C., BETZ, P., et al. (1991). ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY. CHEMISCHE BERICHTE-RECUEIL, 124(12), 2843-2855.
FUCHS, E., BREIT, B., HEYDT, H., Schoeller, W., BUSCH, T., KRUGER, C., BETZ, P., and REGITZ, M. (1991). ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY. CHEMISCHE BERICHTE-RECUEIL 124, 2843-2855.
FUCHS, E., et al., 1991. ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY. CHEMISCHE BERICHTE-RECUEIL, 124(12), p 2843-2855.
E. FUCHS, et al., “ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY”, CHEMISCHE BERICHTE-RECUEIL, vol. 124, 1991, pp. 2843-2855.
FUCHS, E., BREIT, B., HEYDT, H., Schoeller, W., BUSCH, T., KRUGER, C., BETZ, P., REGITZ, M.: ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY. CHEMISCHE BERICHTE-RECUEIL. 124, 2843-2855 (1991).
FUCHS, E, BREIT, B, HEYDT, H, Schoeller, Wolfgang, BUSCH, T, KRUGER, C, BETZ, P, and REGITZ, M. “ORGANOPHOSPHORUS COMPOUNDS .51. PHOSPHATRIAFULVENES - PHOSPHAALKENES WITH INVERSE ELECTRON-DENSITY”. CHEMISCHE BERICHTE-RECUEIL 124.12 (1991): 2843-2855.
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