RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS

Schoeller W, TUBBESING U (1995)
THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE 343: 49-55.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Relative cation and anion stabilities of a selected variety of low-coordinated pi-bonded phosphorus compounds are evaluated for the gas phase by means of group transfer reactions at an ab initio RHF/SCF level with inclusion of electron correlation treatment (MP4SDTQ(fc)/6-31+g(d)). The cation stabilities reveal large variations; the largest cation stabilities are possessed by the diaminophosphenium cation and the phosphanetriylammonium cation. Interestingly the diphosphinophosphenium structure is capable of strong stabilization of the corresponding cation as well as the anion. An analysis of the frontier orbitals indicates that the cationic species can be divided into classes of structures, isolobal with a carbene or a cyanide, isocyanide, rsp.
Erscheinungsjahr
Zeitschriftentitel
THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE
Band
343
Seite
49-55
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Schoeller W, TUBBESING U. RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE. 1995;343:49-55.
Schoeller, W., & TUBBESING, U. (1995). RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE, 343, 49-55. doi:10.1016/0166-1280(95)90523-5
Schoeller, W., and TUBBESING, U. (1995). RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE 343, 49-55.
Schoeller, W., & TUBBESING, U., 1995. RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE, 343, p 49-55.
W. Schoeller and U. TUBBESING, “RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS”, THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE, vol. 343, 1995, pp. 49-55.
Schoeller, W., TUBBESING, U.: RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE. 343, 49-55 (1995).
Schoeller, Wolfgang, and TUBBESING, U. “RELATIVE CATION VERSUS ANION STABILITIES OF LOW-COORDINATED P(III)PI-BONDED PHOSPHORUS-COMPOUNDS”. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE 343 (1995): 49-55.