Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III)

Müller A, Diemann E, Krickemeyer E, Bögge H, Menke C, Kuhlmann C (1996)
MONATSHEFTE FUR CHEMIE 127(1): 43-49.

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Abstract
The structure and packing of the lattice of the compounds (PPh(4))(3)[As(CS3)(3)] (1), (PPh(4))(3)[Bi(CS3)(3)] (2), and (PPh(4))(3)[Fe(CS3)(3)]. H2O (3) is discussed in terms of hostguest chemistry in a ''soft'' matrix of large cations. The hitherto unknown Fe-complex was characterized by elemental analysis and single crystal structure analysis. Here CS32- acts as a classical bidentate ligand, whereas in the case of the arsenic and bismut complexes, the coordination of this ligand is essentially unidentate due to an interaction with the lone pair on the central atom. For the last two complexes, there seems to be an influence of the packing on the coordination geometry.
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Müller A, Diemann E, Krickemeyer E, Bögge H, Menke C, Kuhlmann C. Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE. 1996;127(1):43-49.
Müller, A., Diemann, E., Krickemeyer, E., Bögge, H., Menke, C., & Kuhlmann, C. (1996). Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE, 127(1), 43-49.
Müller, A., Diemann, E., Krickemeyer, E., Bögge, H., Menke, C., and Kuhlmann, C. (1996). Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE 127, 43-49.
Müller, A., et al., 1996. Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE, 127(1), p 43-49.
A. Müller, et al., “Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III)”, MONATSHEFTE FUR CHEMIE, vol. 127, 1996, pp. 43-49.
Müller, A., Diemann, E., Krickemeyer, E., Bögge, H., Menke, C., Kuhlmann, C.: Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE. 127, 43-49 (1996).
Müller, Achim, Diemann, Ekkehard, Krickemeyer, Erich, Bögge, Hartmut, Menke, C, and Kuhlmann, Christoph. “Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III)”. MONATSHEFTE FUR CHEMIE 127.1 (1996): 43-49.
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