Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand

Stammler H-G, Jutzi P, Neumann B, Kristen MO (1995)
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 51(12): 2496-2498.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Autor
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Abstract / Bemerkung
The title compound, tetracarbonylbis{eta(5)-1-[2-(dimethylamino)ethyl]-2,3,4,5-tetramethylcy clopentadienyl}dimolybdenum(Mo-Mo), [Mo-2(C13H22N)(2)(CO)(4)], is the first molybdenum complex incorporating the hemilabile 1-[2-(dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand. The Mo-Mo distance of 2.510 (1) Angstrom is a typical triple-bond distance. The dimethylamino group of the side chain is clearly not coordinated to the metal atom.
Erscheinungsjahr
Zeitschriftentitel
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Band
51
Zeitschriftennummer
12
Seite
2496-2498
ISSN
PUB-ID

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Stammler H-G, Jutzi P, Neumann B, Kristen MO. Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS. 1995;51(12):2496-2498.
Stammler, H. - G., Jutzi, P., Neumann, B., & Kristen, M. O. (1995). Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 51(12), 2496-2498. doi:10.1107/S0108270195006822
Stammler, H. - G., Jutzi, P., Neumann, B., and Kristen, M. O. (1995). Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 51, 2496-2498.
Stammler, H.-G., et al., 1995. Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 51(12), p 2496-2498.
H.-G. Stammler, et al., “Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand”, ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol. 51, 1995, pp. 2496-2498.
Stammler, H.-G., Jutzi, P., Neumann, B., Kristen, M.O.: Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS. 51, 2496-2498 (1995).
Stammler, Hans-Georg, Jutzi, Peter, Neumann, B, and Kristen, MO. “Non-coordination of the dimethylamino group in a dinuclear molybdenum complex with the 1-[2-(dimethylamino)-ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand”. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 51.12 (1995): 2496-2498.