Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones

Weber L, Scheffer MH, Beckmann E-E, Stammler H-G, Neumann B (1997)
Organometallics 16(13): 2958-2962.

Journal Article | Published | English

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Abstract
The metallophosphaalkene (eta(5)-C5Me5)(CO)(2)FeP=C(NMe2)(2) (1) underwent reaction with sydnones 3-aryl-NNOC(O)CH (aryl = C6H5 (2a), 4-FC6H4 (2b), 4-ClC6H4 (2c), 4-BrC6H4 (2d)) to afford the novel ferriophosphaalkenes (eta(5)-C5Me5)(CO)(2)FeP=CHN(aryl)N=C(NMe2)(2) (3a-d). Compound 3a forms the [2 + 2] phosphetanyl cycloadduct 4a with dimethyl fumarate. The molecular structure of 3a was determined by single-crystal X-ray diffraction.
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Weber L, Scheffer MH, Beckmann E-E, Stammler H-G, Neumann B. Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones. Organometallics. 1997;16(13):2958-2962.
Weber, L., Scheffer, M. H., Beckmann, E. - E., Stammler, H. - G., & Neumann, B. (1997). Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones. Organometallics, 16(13), 2958-2962.
Weber, L., Scheffer, M. H., Beckmann, E. - E., Stammler, H. - G., and Neumann, B. (1997). Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones. Organometallics 16, 2958-2962.
Weber, L., et al., 1997. Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones. Organometallics, 16(13), p 2958-2962.
L. Weber, et al., “Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones”, Organometallics, vol. 16, 1997, pp. 2958-2962.
Weber, L., Scheffer, M.H., Beckmann, E.-E., Stammler, H.-G., Neumann, B.: Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones. Organometallics. 16, 2958-2962 (1997).
Weber, Lothar, Scheffer, Matthias H., Beckmann, Eike-Elisabeth, Stammler, Hans-Georg, and Neumann, Beate. “Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (N--N(Ar)-CH+) of sydnones”. Organometallics 16.13 (1997): 2958-2962.
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