Donor complexes of silylene, germylene, and stannylene

Schoeller W, Schneider R (1997)
CHEMISCHE BERICHTE-RECUEIL 130(7): 1013-1020.

Journal Article | Published | English

No fulltext has been uploaded

Author
;
Abstract
The complexes of various donor molecules, AH(3) (A = N, P, As, Sb, Bi) and AH(2) (A = O, S, Se, Te) with silylene, germylene, and stannylene ((1)A(1) ground state) were studied by means of quantum chemical investigations at ab initio level utilizing all valence electron basis sets and relativistic corrected effective core potential methods. Accordingly, the donor molecules are weakly bound, the association energies are in the range of 15-30 kcal per mole. The exothermic energies for adduct formation, i.e., the resulting binding energies for the donor complexes, decrease in the order silylene > germylene > stannylene. The population analysis indicates for NH3 and BiH3 only a weak bonding towards the XH2 fragment (X = Si, Ge, Sn) while the higher homologues (A = P, As, Sb) form ylide structures, 1.2-dipolaric in nature. The addition of two donor molecules has been studied for silylene and is much less favourable than donor mono-addition. For the donor mono-addition a dual parameter relationship between (a) the HOMO energies of the donor (n-orbital of the AH(3) unit, n, p-orbitals for AH(2)) and (b) the covalent bond energies (from the literature) versus the binding energies of the donor-acceptor compounds was examined. This dual parameter equation describes satisfactorily the essential features of the stabilities of the donor-acceptor structures.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Schoeller W, Schneider R. Donor complexes of silylene, germylene, and stannylene. CHEMISCHE BERICHTE-RECUEIL. 1997;130(7):1013-1020.
Schoeller, W., & Schneider, R. (1997). Donor complexes of silylene, germylene, and stannylene. CHEMISCHE BERICHTE-RECUEIL, 130(7), 1013-1020.
Schoeller, W., and Schneider, R. (1997). Donor complexes of silylene, germylene, and stannylene. CHEMISCHE BERICHTE-RECUEIL 130, 1013-1020.
Schoeller, W., & Schneider, R., 1997. Donor complexes of silylene, germylene, and stannylene. CHEMISCHE BERICHTE-RECUEIL, 130(7), p 1013-1020.
W. Schoeller and R. Schneider, “Donor complexes of silylene, germylene, and stannylene”, CHEMISCHE BERICHTE-RECUEIL, vol. 130, 1997, pp. 1013-1020.
Schoeller, W., Schneider, R.: Donor complexes of silylene, germylene, and stannylene. CHEMISCHE BERICHTE-RECUEIL. 130, 1013-1020 (1997).
Schoeller, Wolfgang, and Schneider, R. “Donor complexes of silylene, germylene, and stannylene”. CHEMISCHE BERICHTE-RECUEIL 130.7 (1997): 1013-1020.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar