Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly

Jutzi P, Schneider M, Stammler H-G, Neumann B (1997)
ORGANOMETALLICS 16(24): 5377-5380.

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Abstract
(5-(Trimethylsilyl)cyclopenta-1,3-dien-5-yl)silanetriol, [C5H4(SiMe3)]Si(OH)(3) (2), has been synthesized by controlled hydrolysis of the silicon trichloride [C5H4(SiMe3)]SiCl3 (1) The crystal structure of compound 2 confirms a new structure type for silanetriols: intermolecular hydrogen bonding leads to a highly symmetrical tubelike arrangement. Stannylation of 2 utilizing N(SnMe3)(3) yields [C5H4(SiMe3)]Si(OSnMe3)(3) (3) as a valuable synthon for the silanetriol.
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Jutzi P, Schneider M, Stammler H-G, Neumann B. Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly. ORGANOMETALLICS. 1997;16(24):5377-5380.
Jutzi, P., Schneider, M., Stammler, H. - G., & Neumann, B. (1997). Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly. ORGANOMETALLICS, 16(24), 5377-5380.
Jutzi, P., Schneider, M., Stammler, H. - G., and Neumann, B. (1997). Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly. ORGANOMETALLICS 16, 5377-5380.
Jutzi, P., et al., 1997. Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly. ORGANOMETALLICS, 16(24), p 5377-5380.
P. Jutzi, et al., “Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly”, ORGANOMETALLICS, vol. 16, 1997, pp. 5377-5380.
Jutzi, P., Schneider, M., Stammler, H.-G., Neumann, B.: Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly. ORGANOMETALLICS. 16, 5377-5380 (1997).
Jutzi, Peter, Schneider, M, Stammler, Hans-Georg, and Neumann, B. “Synthesis, derivatization, and structure of the silanetriol [C5H4(SiMe3)]Si(OH)(3): Unique hydrogen bonding in a highly symmetrical tubular assembly”. ORGANOMETALLICS 16.24 (1997): 5377-5380.
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