Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes

Weber L, Scheffer MH, Stammler H-G, Neumann B (1998)
European Journal of Inorganic Chemistry (1): 55-59.

Journal Article | Published | English

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Abstract
Reaction of equimolar amounts of the metalloarsaalkene [(eta(5)-C5Me5)(CO)(2)FeAs=C(NMe2)(2)] (1) with the carbonyl complexes [Ni(CO)(4)], [Fe-2(CO)(9)], and [{(Z)-cyclooctene}Cr(CO)(5)], respectively, affords the adducts [(eta(5)-C5Me5)(CO)(2)FeAs-{M(CO)(n)}=C(NMe2)(2)] with [M(CO)(n)] = [Ni(CO)(3)] (2); [Fe(CO)(4)] (3), and [Cr(CO)(5)] (4). These feature eta(1) coordination of the arsaalkene ligand via the arsenic atom. The molecular structures of the complexes 3 and 4 have been determined by X-ray diffraction analyses.
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Weber L, Scheffer MH, Stammler H-G, Neumann B. Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes. European Journal of Inorganic Chemistry. 1998;(1):55-59.
Weber, L., Scheffer, M. H., Stammler, H. - G., & Neumann, B. (1998). Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes. European Journal of Inorganic Chemistry(1), 55-59.
Weber, L., Scheffer, M. H., Stammler, H. - G., and Neumann, B. (1998). Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes. European Journal of Inorganic Chemistry, 55-59.
Weber, L., et al., 1998. Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes. European Journal of Inorganic Chemistry, (1), p 55-59.
L. Weber, et al., “Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes”, European Journal of Inorganic Chemistry, 1998, pp. 55-59.
Weber, L., Scheffer, M.H., Stammler, H.-G., Neumann, B.: Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes. European Journal of Inorganic Chemistry. 55-59 (1998).
Weber, Lothar, Scheffer, Matthias H., Stammler, Hans-Georg, and Neumann, Beate. “Metalloarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] as a Ligand in Carbonylchromium, -iron and -nickel Complexes”. European Journal of Inorganic Chemistry 1 (1998): 55-59.
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