Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds

Canac Y, Bourissou D, Baceiredo A, Gornitzka H, Schoeller W, Bertrand G (1998)
SCIENCE 279(5359): 2080-2082.

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Abstract
A tetraphosphabenzene analog of the postulated anti-tricyclohexylene, a singlet biradical valence isomer of benzene, has been isolated. The tricyclic derivative features one-electron phosphorus-phosphorus bonds, which result from the pi*-pi* interaction between two diphosphirenyl radicals. Such one-electron bonds may play a wider role in phosphorus chemistry.
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Canac Y, Bourissou D, Baceiredo A, Gornitzka H, Schoeller W, Bertrand G. Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE. 1998;279(5359):2080-2082.
Canac, Y., Bourissou, D., Baceiredo, A., Gornitzka, H., Schoeller, W., & Bertrand, G. (1998). Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE, 279(5359), 2080-2082.
Canac, Y., Bourissou, D., Baceiredo, A., Gornitzka, H., Schoeller, W., and Bertrand, G. (1998). Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE 279, 2080-2082.
Canac, Y., et al., 1998. Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE, 279(5359), p 2080-2082.
Y. Canac, et al., “Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds”, SCIENCE, vol. 279, 1998, pp. 2080-2082.
Canac, Y., Bourissou, D., Baceiredo, A., Gornitzka, H., Schoeller, W., Bertrand, G.: Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE. 279, 2080-2082 (1998).
Canac, Y, Bourissou, D, Baceiredo, A, Gornitzka, H, Schoeller, Wolfgang, and Bertrand, G. “Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds”. SCIENCE 279.5359 (1998): 2080-2082.
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Hubner A, Diehl AM, Diefenbach M, Endeward B, Bolte M, Lerner HW, Holthausen MC, Wagner M., Angew. Chem. Int. Ed. Engl. 53(19), 2014
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Low-valent Ge(2) and Ge(4) species trapped by N-heterocyclic gallylene.
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PMID: 20099287
New adventures in the molecular chemistry of phosphorus.
Russell CA., Angew. Chem. Int. Ed. Engl. 48(27), 2009
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Eta3-diphosphavinylcarbene: a P2 analogue of the Dotz intermediate.
Aktas H, Slootweg JC, Ehlers AW, Lutz M, Spek AL, Lammertsma K., Angew. Chem. Int. Ed. Engl. 48(17), 2009
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Tetraphosphabenzenes obtained via a triphosphacyclobutadiene intermediate.
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Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G., Angew. Chem. Int. Ed. Engl. 44(34), 2005
PMID: 16052642

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