Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand

Schmidt H, Keitemeyer S, Neumann B, Stammler H-G, Schoeller W, Jutzi P (1998)
ORGANOMETALLICS 17(11): 2149-2151.

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Abstract
The 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl (Mamx) ligand allows the synthesis of the germylenes MamxGeCl (I), Mamx(2)Ge (2), Mamx(Tip)Ge (3; Tip = 2,4,6-iPr(3)C(6)H(2)), MamxGeN(3) (4), MamxGeN(SiMe3)(2) (5), and MamxGe[Fe(CO)(2)Cp*] (6), which are all stabilized by coordination of the amino side chain. Reactions of 2 and 3 with Mel yield the ionic compounds Mamx(Tip)(Me)Ge+I-(7) and Mamx(2)(Me)Ge+I- (8), respectively; the X-ray crystal structure of 7 shows a trigonal-planar coordination at the Ge center and a nearly perpendicular Ge-N bond.
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Schmidt H, Keitemeyer S, Neumann B, Stammler H-G, Schoeller W, Jutzi P. Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand. ORGANOMETALLICS. 1998;17(11):2149-2151.
Schmidt, H., Keitemeyer, S., Neumann, B., Stammler, H. - G., Schoeller, W., & Jutzi, P. (1998). Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand. ORGANOMETALLICS, 17(11), 2149-2151.
Schmidt, H., Keitemeyer, S., Neumann, B., Stammler, H. - G., Schoeller, W., and Jutzi, P. (1998). Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand. ORGANOMETALLICS 17, 2149-2151.
Schmidt, H., et al., 1998. Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand. ORGANOMETALLICS, 17(11), p 2149-2151.
H. Schmidt, et al., “Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand”, ORGANOMETALLICS, vol. 17, 1998, pp. 2149-2151.
Schmidt, H., Keitemeyer, S., Neumann, B., Stammler, H.-G., Schoeller, W., Jutzi, P.: Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand. ORGANOMETALLICS. 17, 2149-2151 (1998).
Schmidt, H, Keitemeyer, S, Neumann, B, Stammler, Hans-Georg, Schoeller, Wolfgang, and Jutzi, Peter. “Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand”. ORGANOMETALLICS 17.11 (1998): 2149-2151.
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