Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-)

Müller A, Koop M, Bögge H, Schmidtmann M, Beugholt C (1998)
CHEMICAL COMMUNICATIONS (15): 1501-1502.

Journal Article | Published | English

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Abstract
The synthesis of 1a.(32 - n)Na+.ca. 600 H2O.ca. 30 CH3OH 1 containing the ring-shaped, mixed-valence (Mo-V/Mo-VI) cluster [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32 - n)-) 1a as a discrete unit in the crystal lattice is reported, which for the first time yields a compound of this type via a facile synthetic method and without amorphous reaction products; remarkably, H2O ligands can be replaced by CH3OH on the surface of a giant metal-oxide based cluster which has a nanometer sized cavity and, in contrast to zeolites, reducing properties.
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Müller A, Koop M, Bögge H, Schmidtmann M, Beugholt C. Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-). CHEMICAL COMMUNICATIONS. 1998;(15):1501-1502.
Müller, A., Koop, M., Bögge, H., Schmidtmann, M., & Beugholt, C. (1998). Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-). CHEMICAL COMMUNICATIONS(15), 1501-1502.
Müller, A., Koop, M., Bögge, H., Schmidtmann, M., and Beugholt, C. (1998). Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-). CHEMICAL COMMUNICATIONS, 1501-1502.
Müller, A., et al., 1998. Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-). CHEMICAL COMMUNICATIONS, (15), p 1501-1502.
A. Müller, et al., “Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-)”, CHEMICAL COMMUNICATIONS, 1998, pp. 1501-1502.
Müller, A., Koop, M., Bögge, H., Schmidtmann, M., Beugholt, C.: Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-). CHEMICAL COMMUNICATIONS. 1501-1502 (1998).
Müller, Achim, Koop, M, Bögge, Hartmut, Schmidtmann, Marc, and Beugholt, Christian. “Exchanged ligands on the surface of a giant cluster: [(MoO3)(176)(H2O)(63)(CH3OH)(17)H-n]((32-n)-)”. CHEMICAL COMMUNICATIONS 15 (1998): 1501-1502.
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