From simple linkable building blocks to structures with increasing size and complexity

Müller A, Kögerler P (1998)
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 46(3): 207-219.

Journal Article | Published | English

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Abstract
Polyoxometalates provide excellent models for the understanding of basic aspects of molecular growth processes: Using the same reaction, i.e., the acidification of the aqueous solution of oxoanions, the resulting products span three important areas of matter, from the micro-, through the meso- to the macro"cosmos", the latter of which is characterized by crystallinity or respectively, translational invariance. Upon different types of linking of well-defined building units an overwhelming variety of different species can be formed. Novel types of molecular growth processes (including those based on a type of induced cascade) are described leading to different ring-shaped, electron-rich, mixed-valence, giant polyoxomolybdates with nano-sized cavities. The recent synthesis of various large ring-duster systems has, furthermore, opened new perspectives for a novel supramolecular chemistry in nano-scale dimensions.
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Müller A, Kögerler P. From simple linkable building blocks to structures with increasing size and complexity. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY. 1998;46(3):207-219.
Müller, A., & Kögerler, P. (1998). From simple linkable building blocks to structures with increasing size and complexity. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 46(3), 207-219.
Müller, A., and Kögerler, P. (1998). From simple linkable building blocks to structures with increasing size and complexity. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 46, 207-219.
Müller, A., & Kögerler, P., 1998. From simple linkable building blocks to structures with increasing size and complexity. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 46(3), p 207-219.
A. Müller and P. Kögerler, “From simple linkable building blocks to structures with increasing size and complexity”, BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, vol. 46, 1998, pp. 207-219.
Müller, A., Kögerler, P.: From simple linkable building blocks to structures with increasing size and complexity. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY. 46, 207-219 (1998).
Müller, Achim, and Kögerler, Paul. “From simple linkable building blocks to structures with increasing size and complexity”. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 46.3 (1998): 207-219.
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