Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-)

Müller A, Krickemeyer E, Bögge H, Schmidtmann M, Beugholt C, Das SK, Peters F (1999)
CHEMISTRY-A EUROPEAN JOURNAL 5(5): 1496-1502.

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Abstract
The synthesis of multifunctional inorganic materials from robust building blocks (synthons) that have a well-defined structure and can be linked together represents a constant challenge in crystal engineering. We report the synthesis of the deep blue mixed-valence (Mo-VI/Mo-V) compound Na-16-[(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)]. ca. 300 H2O (1). which consists of nanosized wheel-shaped building blocks with 152 Mo atoms. These discrete building blocks can be prepared easily by reduction of an acidified aqueous molybdate solution and, when linked together, they form a layered open framework with nanosized channels. The encapsulated water molecules can be partly replaced by organic molecules. The metal-oxide-based host lattice has altogether 28 4d electrons per ring. These can be assigned to 14 incomplete double-cubane-type compartments spanned by five Mo and six O atoms, which show negligible electronic interaction. The two electrons delocalized in each of these compartments give rise to the deep blue colour.
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Müller A, Krickemeyer E, Bögge H, et al. Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-). CHEMISTRY-A EUROPEAN JOURNAL. 1999;5(5):1496-1502.
Müller, A., Krickemeyer, E., Bögge, H., Schmidtmann, M., Beugholt, C., Das, S. K., & Peters, F. (1999). Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-). CHEMISTRY-A EUROPEAN JOURNAL, 5(5), 1496-1502.
Müller, A., Krickemeyer, E., Bögge, H., Schmidtmann, M., Beugholt, C., Das, S. K., and Peters, F. (1999). Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-). CHEMISTRY-A EUROPEAN JOURNAL 5, 1496-1502.
Müller, A., et al., 1999. Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-). CHEMISTRY-A EUROPEAN JOURNAL, 5(5), p 1496-1502.
A. Müller, et al., “Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-)”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 5, 1999, pp. 1496-1502.
Müller, A., Krickemeyer, E., Bögge, H., Schmidtmann, M., Beugholt, C., Das, S.K., Peters, F.: Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-). CHEMISTRY-A EUROPEAN JOURNAL. 5, 1496-1502 (1999).
Müller, Achim, Krickemeyer, Erich, Bögge, Hartmut, Schmidtmann, Marc, Beugholt, Christian, Das, Samar K., and Peters, F. “Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [(Mo124Mo28O429)-Mo-VI-O-V(mu(3)-O)(28)H-14(H2O)(66.5)](16-)”. CHEMISTRY-A EUROPEAN JOURNAL 5.5 (1999): 1496-1502.
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