A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-)

Müller A, Fedin VP, Kuhlmann C, Bögge H, Schmidtmann M (1999)
CHEMICAL COMMUNICATIONS (10): 927-929.

Journal Article | Published | English

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Abstract
By reacting an aqueous solution of ammonium heptamolybdate with formic acid in the presence of hydrazinium sulfate at pH approximate to 4.2 the compound (NH4)(42)[(Mo72Mo60V)-Mo-VI-O-372(HCO2)(30)(H2O)(72)]. xHCO(2)Na . yH(2)O 1 (x approximate to 30, y approximate to 250) with spherically shaped stable cluster anions is obtained; owing to the spherical shape of the cluster-shell template, the anion 1a (with the small 'nondisturbing' bidentate HCO2- ligand) exhibits a remarkable overall 'onion-type' structure, thereby revealing also a novel type of inclusion: a hydrogen-bonded cluster with 'onion-type' structure, which suggests interesting aspects for a new type of supramolecular chemistry.
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Müller A, Fedin VP, Kuhlmann C, Bögge H, Schmidtmann M. A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-). CHEMICAL COMMUNICATIONS. 1999;(10):927-929.
Müller, A., Fedin, V. P., Kuhlmann, C., Bögge, H., & Schmidtmann, M. (1999). A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-). CHEMICAL COMMUNICATIONS(10), 927-929.
Müller, A., Fedin, V. P., Kuhlmann, C., Bögge, H., and Schmidtmann, M. (1999). A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-). CHEMICAL COMMUNICATIONS, 927-929.
Müller, A., et al., 1999. A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-). CHEMICAL COMMUNICATIONS, (10), p 927-929.
A. Müller, et al., “A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-)”, CHEMICAL COMMUNICATIONS, 1999, pp. 927-929.
Müller, A., Fedin, V.P., Kuhlmann, C., Bögge, H., Schmidtmann, M.: A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-). CHEMICAL COMMUNICATIONS. 927-929 (1999).
Müller, Achim, Fedin, Vladimir P., Kuhlmann, Christoph, Bögge, Hartmut, and Schmidtmann, Marc. “A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H2O)(n) subset of (Mo72Mo60O372)-Mo-VI-O-V(HCO2)(30)(H2O)(72)](42-)”. CHEMICAL COMMUNICATIONS 10 (1999): 927-929.
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