Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo)

Jutzi P, Neumann B, Schebaum LO, Stammler A, Stammler H-G (1999)
ORGANOMETALLICS 18(21): 4462-4464.

Journal Article | Published | English

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Abstract
In the reaction of (eta(5)-pentamethylcyclopentadienyl)gallium (Cp*Ga) with Ni(COD)(2) (COD = 1,5-cyclooctadiene) and NorM(CO)(4) (Nor = norbornadiene; M = Cr, Mo) the complexes Ni(Cp*Ga)(4) (1) and cis- M(Cp*Ga)(2)(CO)(4) (M = Cr (2), Mo (3)), respectively, were obtained, Compounds 1-3 were characterized by NMR and IR data and by elemental analysis. In addition, an X-ray crystal structure analysis was performed on complexes 1 and 3. Cis-orientation of the Cp*Ga ligands is made possible by deviation of the Cp-centroid*-Ga-M vector from linearity. 1 is the first homoleptic complex with Cp*Ga as ligand.
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Jutzi P, Neumann B, Schebaum LO, Stammler A, Stammler H-G. Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo). ORGANOMETALLICS. 1999;18(21):4462-4464.
Jutzi, P., Neumann, B., Schebaum, L. O., Stammler, A., & Stammler, H. - G. (1999). Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo). ORGANOMETALLICS, 18(21), 4462-4464.
Jutzi, P., Neumann, B., Schebaum, L. O., Stammler, A., and Stammler, H. - G. (1999). Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo). ORGANOMETALLICS 18, 4462-4464.
Jutzi, P., et al., 1999. Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo). ORGANOMETALLICS, 18(21), p 4462-4464.
P. Jutzi, et al., “Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo)”, ORGANOMETALLICS, vol. 18, 1999, pp. 4462-4464.
Jutzi, P., Neumann, B., Schebaum, L.O., Stammler, A., Stammler, H.-G.: Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo). ORGANOMETALLICS. 18, 4462-4464 (1999).
Jutzi, Peter, Neumann, B, Schebaum, LO, Stammler, A, and Stammler, Hans-Georg. “Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo)”. ORGANOMETALLICS 18.21 (1999): 4462-4464.
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