Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH

Müller A, Beugholt C, Koop M, Das SK, Schmidtmann M, Bögge H (1999)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625(12): 1960-1962.

Journal Article | Published | English

No fulltext has been uploaded

Author
; ; ; ; ;
Abstract
The syntheses and structures of the two mixed-valence crystalline molybdenum blue compounds Na-26[Mo142O432(H2O)(58)H-14] ca. 300H(2)O (1) (containing the maximal number of well defined defects which influence the overall structure and the reactivity of the anionic cluster) and Na-16[(MoO3)(176)(H2O)(63)(CH3OH)(17)H-16].ca. 600H(2)O ca. 6 CH3OH (2) (obtained in an optimized high-yield synthesis) are reported with reference to the critical conditions required for the isolation of corresponding crystalline materials.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Müller A, Beugholt C, Koop M, Das SK, Schmidtmann M, Bögge H. Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 1999;625(12):1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S. K., Schmidtmann, M., & Bögge, H. (1999). Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 625(12), 1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S. K., Schmidtmann, M., and Bögge, H. (1999). Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625, 1960-1962.
Müller, A., et al., 1999. Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 625(12), p 1960-1962.
A. Müller, et al., “Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 625, 1999, pp. 1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S.K., Schmidtmann, M., Bögge, H.: Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 625, 1960-1962 (1999).
Müller, Achim, Beugholt, Christian, Koop, M, Das, Samar K., Schmidtmann, Marc, and Bögge, Hartmut. “Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625.12 (1999): 1960-1962.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar