Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH

Müller A, Beugholt C, Koop M, Das SK, Schmidtmann M, Bögge H (1999)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625(12): 1960-1962.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The syntheses and structures of the two mixed-valence crystalline molybdenum blue compounds Na-26[Mo142O432(H2O)(58)H-14] ca. 300H(2)O (1) (containing the maximal number of well defined defects which influence the overall structure and the reactivity of the anionic cluster) and Na-16[(MoO3)(176)(H2O)(63)(CH3OH)(17)H-16].ca. 600H(2)O ca. 6 CH3OH (2) (obtained in an optimized high-yield synthesis) are reported with reference to the critical conditions required for the isolation of corresponding crystalline materials.
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Zeitschriftentitel
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Band
625
Zeitschriftennummer
12
Seite
1960-1962
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Müller A, Beugholt C, Koop M, Das SK, Schmidtmann M, Bögge H. Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 1999;625(12):1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S. K., Schmidtmann, M., & Bögge, H. (1999). Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 625(12), 1960-1962. doi:10.1002/(SICI)1521-3749(199912)625:12<1960::AID-ZAAC1960>3.0.CO;2-A
Müller, A., Beugholt, C., Koop, M., Das, S. K., Schmidtmann, M., and Bögge, H. (1999). Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625, 1960-1962.
Müller, A., et al., 1999. Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 625(12), p 1960-1962.
A. Müller, et al., “Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 625, 1999, pp. 1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S.K., Schmidtmann, M., Bögge, H.: Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 625, 1960-1962 (1999).
Müller, Achim, Beugholt, Christian, Koop, M, Das, Samar K., Schmidtmann, Marc, and Bögge, Hartmut. “Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625.12 (1999): 1960-1962.