Sandwich-type cyclopentadienyl complexes of main-group elements

Jutzi P (1999)
CHEMIE IN UNSERER ZEIT 33(6): 342-353.

Journal Article | Published | English

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Abstract
Cyclopentadienyl (Cp) complexes of main-group elements are classified and compared in terms of structural types, bonding features, and characteristic reactions. Halfsandwich, sandwich and multidecker sandwich arrangements of different type are observed Including cluster species with weak or strong metal-metal bonds. The Cp-E1 bonding ranges from mainly covalent to purely ionic with important structure-determining inter molecular contacts in the latter. pi-Complexation allows the stabilisation of compounds with low-valent elements such as Al(I), Ga(I), and Si(II). Important reaction principles and applications are shortly described.
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Jutzi P. Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT. 1999;33(6):342-353.
Jutzi, P. (1999). Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT, 33(6), 342-353.
Jutzi, P. (1999). Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT 33, 342-353.
Jutzi, P., 1999. Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT, 33(6), p 342-353.
P. Jutzi, “Sandwich-type cyclopentadienyl complexes of main-group elements”, CHEMIE IN UNSERER ZEIT, vol. 33, 1999, pp. 342-353.
Jutzi, P.: Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT. 33, 342-353 (1999).
Jutzi, Peter. “Sandwich-type cyclopentadienyl complexes of main-group elements”. CHEMIE IN UNSERER ZEIT 33.6 (1999): 342-353.
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