On the electronic properties of substituted phosphanylcarbenes

Schoeller W (2000)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2): 369-374.

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Abstract
A phosphanyl group exerts much less pi-conjugation properties than an amino group. On this basis, corresponding carbene structures exhibit much smaller singlet-triplet energy separations. Of the various structures investigated quantum-chemically the largest singlet-triplet energy separations are predicted for cyclic diphosphanylcarbenes, in which the two functional groups are incorporated into a ring system and the phosphorus atoms are substituted by phosphoraniminato groups. Then the singlet-triplet energy separations become essentially larger than for the Bertrand type (push-pull) carbenes.
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Schoeller W. On the electronic properties of substituted phosphanylcarbenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2000;(2):369-374.
Schoeller, W. (2000). On the electronic properties of substituted phosphanylcarbenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(2), 369-374.
Schoeller, W. (2000). On the electronic properties of substituted phosphanylcarbenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 369-374.
Schoeller, W., 2000. On the electronic properties of substituted phosphanylcarbenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (2), p 369-374.
W. Schoeller, “On the electronic properties of substituted phosphanylcarbenes”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, pp. 369-374.
Schoeller, W.: On the electronic properties of substituted phosphanylcarbenes. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 369-374 (2000).
Schoeller, Wolfgang. “On the electronic properties of substituted phosphanylcarbenes”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2 (2000): 369-374.
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