Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes

Müller C, Jutzi P (2000)
Synthesis 2000(3): 389-394.

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[2-(N,N-Dialkylamino)ethy]cyclopentadienes have been used for the synthesis of the novel amino-functionalized silicon- and carbon-bridged cyclopentadiene derivatives 3a-c, 7, 10 and 13a-c. The C-C and C-Si coupling reactions described here are regioselective leading exclusively to the formation of 1,3-disubstituted isomers, as proven by H-1 NMR spectroscopy. The bis-cyclopentadienes 3a-c, 7, 10 and 13a-c can be deprotonated to the corresponding dianionic species.
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Müller C, Jutzi P. Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis. 2000;2000(3):389-394.
Müller, C., & Jutzi, P. (2000). Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis, 2000(3), 389-394. doi:10.1055/s-2000-6341
Müller, C., and Jutzi, P. (2000). Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis 2000, 389-394.
Müller, C., & Jutzi, P., 2000. Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis, 2000(3), p 389-394.
C. Müller and P. Jutzi, “Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes”, Synthesis, vol. 2000, 2000, pp. 389-394.
Müller, C., Jutzi, P.: Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis. 2000, 389-394 (2000).
Müller, Christian, and Jutzi, Peter. “Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes”. Synthesis 2000.3 (2000): 389-394.
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