Environmental effects on big molecule with spin 1/2

Chiorescu I, Wernsdorfer W, Barbara B, Müller A, Bögge H (2000)
JOURNAL OF APPLIED PHYSICS 87(9): 5496-5498.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The V-15 polyoxovanadate molecule is made of 15 spins 1/2 with antiferromagnetic couplings. It is a low spin/big molecule with spin S=1/2. Contrary to large spins/big molecules of the Mn-12-ac type, V-15 has no energy barrier against spin rotation. Nevertheless, it shows magnetic hysteresis. This new phenomenon characterized by a "butterfly" hysteresis loop is due to the effect of the environment on the quantum rotation of the entangled 15 spins of the molecule, in which the phonon density of states is not at its equilibrium (phonon bottleneck). This behavior is very likely specific to big molecules with low spin. (C) 2000 American Institute of Physics. [S0021-8979(00)31908-9].
Erscheinungsjahr
Zeitschriftentitel
JOURNAL OF APPLIED PHYSICS
Band
87
Zeitschriftennummer
9
Seite
5496-5498
ISSN
PUB-ID

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Chiorescu I, Wernsdorfer W, Barbara B, Müller A, Bögge H. Environmental effects on big molecule with spin 1/2. JOURNAL OF APPLIED PHYSICS. 2000;87(9):5496-5498.
Chiorescu, I., Wernsdorfer, W., Barbara, B., Müller, A., & Bögge, H. (2000). Environmental effects on big molecule with spin 1/2. JOURNAL OF APPLIED PHYSICS, 87(9), 5496-5498. doi:10.1063/1.373383
Chiorescu, I., Wernsdorfer, W., Barbara, B., Müller, A., and Bögge, H. (2000). Environmental effects on big molecule with spin 1/2. JOURNAL OF APPLIED PHYSICS 87, 5496-5498.
Chiorescu, I., et al., 2000. Environmental effects on big molecule with spin 1/2. JOURNAL OF APPLIED PHYSICS, 87(9), p 5496-5498.
I. Chiorescu, et al., “Environmental effects on big molecule with spin 1/2”, JOURNAL OF APPLIED PHYSICS, vol. 87, 2000, pp. 5496-5498.
Chiorescu, I., Wernsdorfer, W., Barbara, B., Müller, A., Bögge, H.: Environmental effects on big molecule with spin 1/2. JOURNAL OF APPLIED PHYSICS. 87, 5496-5498 (2000).
Chiorescu, I, Wernsdorfer, W, Barbara, B, Müller, Achim, and Bögge, Hartmut. “Environmental effects on big molecule with spin 1/2”. JOURNAL OF APPLIED PHYSICS 87.9 (2000): 5496-5498.