Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane

Dullaghan CA, Carpenter GB, Sweigart DA, Kuck D, Fusco C, Curci R (2000)
ORGANOMETALLICS 19(11): 2233-2236.

Journal Article | Published | English

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Abstract
The cationic manganese tricarbonyl moiety is readily coordinated to an arene ring of the centropolyindanes 10-methyltribenzotriquinacene (MTBT) and fenestrindane (FET) to afford [(MTBT)Mn(CO)(3)](+) (1) and [(FET)Mn(CO)(3)](+) (2). An X-ray structure of 1 shows that the metal is coordinated to the convex face of the MTBT ligand. Both 1 and 2 are electrophilically activated and readily undergo regioselective and stereoselective addition reactions with mild nucleophiles.
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Dullaghan CA, Carpenter GB, Sweigart DA, Kuck D, Fusco C, Curci R. Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane. ORGANOMETALLICS. 2000;19(11):2233-2236.
Dullaghan, C. A., Carpenter, G. B., Sweigart, D. A., Kuck, D., Fusco, C., & Curci, R. (2000). Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane. ORGANOMETALLICS, 19(11), 2233-2236.
Dullaghan, C. A., Carpenter, G. B., Sweigart, D. A., Kuck, D., Fusco, C., and Curci, R. (2000). Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane. ORGANOMETALLICS 19, 2233-2236.
Dullaghan, C.A., et al., 2000. Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane. ORGANOMETALLICS, 19(11), p 2233-2236.
C.A. Dullaghan, et al., “Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane”, ORGANOMETALLICS, vol. 19, 2000, pp. 2233-2236.
Dullaghan, C.A., Carpenter, G.B., Sweigart, D.A., Kuck, D., Fusco, C., Curci, R.: Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane. ORGANOMETALLICS. 19, 2233-2236 (2000).
Dullaghan, C. A., Carpenter, G. B., Sweigart, D. A., Kuck, Dietmar, Fusco, C., and Curci, R. “Synthesis and reactivity of manganese tricarbonyl complexes of the centropolyindanes 10-methyltribenzotriquinacene and fenestrindane”. ORGANOMETALLICS 19.11 (2000): 2233-2236.
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