New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene

Theil M, Jutzi P, Neumann B, Stammler A, Stammler H-G (2000)
ORGANOMETALLICS 19(15): 2937-2940.

Journal Article | Published | English

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Abstract
Formation of mercury-silicon bonds was effected in the reaction of the mercury halides HgCl2 HgBr2, and Hg2Cl2 with decamethylsilicocene, Cp*Si-2 (1). Depending on the ratio of the reactants, the single-and double-insertion products (Cp*2SiX)HgX(2, X = Cl; 3, X = Br) and (Cp*2SiX)(2)Hg (4, X = Cl; 5, X = Br), respectively, were obtained. The novel compounds were characterized by H-1, C-13, and Si-29 NMR spectroscopic data and, in the case of 2 and 5, also by an X-ray crystal structure analysis.
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Theil M, Jutzi P, Neumann B, Stammler A, Stammler H-G. New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene. ORGANOMETALLICS. 2000;19(15):2937-2940.
Theil, M., Jutzi, P., Neumann, B., Stammler, A., & Stammler, H. - G. (2000). New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene. ORGANOMETALLICS, 19(15), 2937-2940.
Theil, M., Jutzi, P., Neumann, B., Stammler, A., and Stammler, H. - G. (2000). New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene. ORGANOMETALLICS 19, 2937-2940.
Theil, M., et al., 2000. New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene. ORGANOMETALLICS, 19(15), p 2937-2940.
M. Theil, et al., “New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene”, ORGANOMETALLICS, vol. 19, 2000, pp. 2937-2940.
Theil, M., Jutzi, P., Neumann, B., Stammler, A., Stammler, H.-G.: New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene. ORGANOMETALLICS. 19, 2937-2940 (2000).
Theil, M, Jutzi, Peter, Neumann, B, Stammler, A, and Stammler, Hans-Georg. “New approach to silylmercury compounds by reaction of mercury halides with decamethylsilicocene”. ORGANOMETALLICS 19.15 (2000): 2937-2940.
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