Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface

Müller A, Beugholt C, Bögge H, Schmidtmann M (2000)
INORGANIC CHEMISTRY 39(15): 3112-3113.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
A new type of giant-wheel-shaped anion (see title) is obtained during the formation of the "classical" tetradecameric molybdenum-blue-type species [{Mo-2){Mo-8}{Mo-1}](14) in the presence of Pr3+. The Pr3+ cations substitute {Mo-2} units and thereby increase the curvature of each ring, which leads to destruction and smaller ring sizes.
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INORGANIC CHEMISTRY
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39
Zeitschriftennummer
15
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3112-3113
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Müller A, Beugholt C, Bögge H, Schmidtmann M. Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY. 2000;39(15):3112-3113.
Müller, A., Beugholt, C., Bögge, H., & Schmidtmann, M. (2000). Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY, 39(15), 3112-3113. doi:10.1021/ic000168l
Müller, A., Beugholt, C., Bögge, H., and Schmidtmann, M. (2000). Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY 39, 3112-3113.
Müller, A., et al., 2000. Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY, 39(15), p 3112-3113.
A. Müller, et al., “Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface”, INORGANIC CHEMISTRY, vol. 39, 2000, pp. 3112-3113.
Müller, A., Beugholt, C., Bögge, H., Schmidtmann, M.: Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY. 39, 3112-3113 (2000).
Müller, Achim, Beugholt, Christian, Bögge, Hartmut, and Schmidtmann, Marc. “Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface”. INORGANIC CHEMISTRY 39.15 (2000): 3112-3113.

13 Zitationen in Europe PMC

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Polyoxotungstate-encapsulated Gd(6) and Yb(10) complexes.
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Caesium-templated lanthanoid-containing polyoxotungstates.
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