Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds

Vos D, Salmon A, Stammler H-G, Neumann B, Jutzi P (2000)
ORGANOMETALLICS 19(19): 3874-3878.

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Abstract
The synthesis of the 1,1',3,3'-tetrabutenyl-substituted metallocenes [C5H3(CMe2CH2CH= CH2)(2)](2)M (M = Fe 1, Co 2, Ni 3), their electrochemical properties, and the solid-state structures of 1 and 3 are presented. Hydrosilylation of 1 with dimethylphenylsilane leads to [C5H3(CMe2(CH2)(3)SiMe2Ph)(2)](2)Fe, 4. The pi-coordination ability of the arene system in 4 has allowed the preparation of the pentanuclear complex [C5H3(CMe2(CH2)(3)SiMe2(eta(6)-C6H5-Cr(CO)(3))(2)](2)Fe, 5, containing a ferrocene core and peripherial eta(6)-coordinated Cr(CO)(3) moieties. Electrochemical investigations of 5 show a reversible oxidation of the ferrocene unit as well as an independent, noninteracting irreversible oxidation of the Cr centers.
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Vos D, Salmon A, Stammler H-G, Neumann B, Jutzi P. Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds. ORGANOMETALLICS. 2000;19(19):3874-3878.
Vos, D., Salmon, A., Stammler, H. - G., Neumann, B., & Jutzi, P. (2000). Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds. ORGANOMETALLICS, 19(19), 3874-3878.
Vos, D., Salmon, A., Stammler, H. - G., Neumann, B., and Jutzi, P. (2000). Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds. ORGANOMETALLICS 19, 3874-3878.
Vos, D., et al., 2000. Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds. ORGANOMETALLICS, 19(19), p 3874-3878.
D. Vos, et al., “Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds”, ORGANOMETALLICS, vol. 19, 2000, pp. 3874-3878.
Vos, D., Salmon, A., Stammler, H.-G., Neumann, B., Jutzi, P.: Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds. ORGANOMETALLICS. 19, 3874-3878 (2000).
Vos, D, Salmon, A, Stammler, Hans-Georg, Neumann, B, and Jutzi, Peter. “Synthesis of tetra-3-butenyl-substituted metallocenes and the application of 1,1 ',3,3 '-tetrakis(1,1-dimethyl-3-butenyl)ferrocene as core for the preparation of polynuclear compounds”. ORGANOMETALLICS 19.19 (2000): 3874-3878.
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