[(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism

Müller A, Beugholt C, Kögerler P, Bögge H, Bud'ko S, Luban M (2000)
Inorganic Chemistry 39(23): 5176-5177.

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The novel title compound {(Ni4Mo12v)-Mo-II} demonstrates the concept of generating targeted spin topologies using reduced polyoxometalates: The four electrophilic nickel centers-forming a tetrahedron-are fixed by a nucleophilic highly reduced diamagnetic epsilon -Keggin cluster of T-d symmetry generated in solution. This cluster not only has a structural role but actually participates in the transmission of the exchange interaction.
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Müller A, Beugholt C, Kögerler P, Bögge H, Bud'ko S, Luban M. [(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism. Inorganic Chemistry. 2000;39(23):5176-5177.
Müller, A., Beugholt, C., Kögerler, P., Bögge, H., Bud'ko, S., & Luban, M. (2000). [(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism. Inorganic Chemistry, 39(23), 5176-5177.
Müller, A., Beugholt, C., Kögerler, P., Bögge, H., Bud'ko, S., and Luban, M. (2000). [(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism. Inorganic Chemistry 39, 5176-5177.
Müller, A., et al., 2000. [(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism. Inorganic Chemistry, 39(23), p 5176-5177.
A. Müller, et al., “[(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism”, Inorganic Chemistry, vol. 39, 2000, pp. 5176-5177.
Müller, A., Beugholt, C., Kögerler, P., Bögge, H., Bud'ko, S., Luban, M.: [(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism. Inorganic Chemistry. 39, 5176-5177 (2000).
Müller, Achim, Beugholt, Christian, Kögerler, Paul, Bögge, Hartmut, Bud'ko, S, and Luban, M. “[(Mo12O30)-O-V(mu(2)-OH)(10)H-2{Ni-II(H2O)3}4], a highly symmetrical epsilon-Keggin unit capped with four Ni-II centers: Synthesis and magnetism”. Inorganic Chemistry 39.23 (2000): 5176-5177.
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