A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes

Schmoldt P, Mattay J (2000)
In: JOURNAL OF INFORMATION RECORDING. 25. GORDON BREACH SCI PUBL LTD: 239-243.

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Abstract
Photoinduced electron transfer (PET) from triethylamine (TEA) to alpha -cyclopropyl ketones initiates a cyclopropylcarbinyl-homoallyl rearrangement. The resulting homoallyl radical can be used in cyclization reactions with unsaturated side chains present in the starting material. Thus a variety of bicyclic products is accessible depending on the position and length of the side chain. The synthesis of suitable alpha -cyclopropyl ketone precursors is achieved via oxa-di-pi -methane rearrangement.
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Schmoldt P, Mattay J. A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. In: JOURNAL OF INFORMATION RECORDING. Vol 25. GORDON BREACH SCI PUBL LTD; 2000: 239-243.
Schmoldt, P., & Mattay, J. (2000). A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING, 25(1-2), 239-243.
Schmoldt, P., and Mattay, J. (2000). “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes” in JOURNAL OF INFORMATION RECORDING, vol. 25, (GORDON BREACH SCI PUBL LTD), 239-243.
Schmoldt, P., & Mattay, J., 2000. A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. In JOURNAL OF INFORMATION RECORDING. no.25 GORDON BREACH SCI PUBL LTD, pp. 239-243.
P. Schmoldt and J. Mattay, “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes”, JOURNAL OF INFORMATION RECORDING, vol. 25, GORDON BREACH SCI PUBL LTD, 2000, pp.239-243.
Schmoldt, P., Mattay, J.: A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING. 25, p. 239-243. GORDON BREACH SCI PUBL LTD (2000).
Schmoldt, P, and Mattay, Jochen. “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes”. JOURNAL OF INFORMATION RECORDING. GORDON BREACH SCI PUBL LTD, 2000.Vol. 25. 239-243.
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