A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes

Schmoldt P, Mattay J (2000)
JOURNAL OF INFORMATION RECORDING 25(1-2): 239-243.

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Konferenzbeitrag | Veröffentlicht | Englisch
Autor
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Abstract / Bemerkung
Photoinduced electron transfer (PET) from triethylamine (TEA) to alpha -cyclopropyl ketones initiates a cyclopropylcarbinyl-homoallyl rearrangement. The resulting homoallyl radical can be used in cyclization reactions with unsaturated side chains present in the starting material. Thus a variety of bicyclic products is accessible depending on the position and length of the side chain. The synthesis of suitable alpha -cyclopropyl ketone precursors is achieved via oxa-di-pi -methane rearrangement.
Erscheinungsjahr
Band
25
Zeitschriftennummer
1-2
Seite
239-243
ISSN
PUB-ID

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Schmoldt P, Mattay J. A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING. 2000;25(1-2):239-243.
Schmoldt, P., & Mattay, J. (2000). A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING, 25(1-2), 239-243.
Schmoldt, P., and Mattay, J. (2000). A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING 25, 239-243.
Schmoldt, P., & Mattay, J., 2000. A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING, 25(1-2), p 239-243.
P. Schmoldt and J. Mattay, “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes”, JOURNAL OF INFORMATION RECORDING, vol. 25, 2000, pp. 239-243.
Schmoldt, P., Mattay, J.: A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING. 25, 239-243 (2000).
Schmoldt, P, and Mattay, Jochen. “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes”. JOURNAL OF INFORMATION RECORDING 25.1-2 (2000): 239-243.