PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions

Rinderhagen H, Grota J, Mattay J (2000)
JOURNAL OF INFORMATION RECORDING 25(1-2): 229-233.

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Konferenzbeitrag | Veröffentlicht | Englisch
Autor
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Abstract / Bemerkung
Siloxy cyclopropanes are easily oxidizable by photoinduced electron transfer (PET) reagents. The fragmentation of the resulting radical cations leads to beta -ketoradicals. The usability of these radicals in intermolecular addition reactions is limited by polymerisation or reduction. This disadvantage can be partially circumvented by studying the influence of the concentration of the reaction partners.
Erscheinungsjahr
Band
25
Zeitschriftennummer
1-2
Seite
229-233
ISSN
PUB-ID

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Rinderhagen H, Grota J, Mattay J. PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING. 2000;25(1-2):229-233.
Rinderhagen, H., Grota, J., & Mattay, J. (2000). PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING, 25(1-2), 229-233.
Rinderhagen, H., Grota, J., and Mattay, J. (2000). PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING 25, 229-233.
Rinderhagen, H., Grota, J., & Mattay, J., 2000. PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING, 25(1-2), p 229-233.
H. Rinderhagen, J. Grota, and J. Mattay, “PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions”, JOURNAL OF INFORMATION RECORDING, vol. 25, 2000, pp. 229-233.
Rinderhagen, H., Grota, J., Mattay, J.: PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING. 25, 229-233 (2000).
Rinderhagen, H, Grota, J, and Mattay, Jochen. “PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions”. JOURNAL OF INFORMATION RECORDING 25.1-2 (2000): 229-233.