[60]fullerene radical cation reactions and mechanism

Siedschlag C, Dunsch L, Ito O, Mattay J (2000)
In: JOURNAL OF INFORMATION RECORDING. 25. GORDON BREACH SCI PUBL LTD: 265-271.

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Abstract
[60]Fullerene is oxidized to its radical cation at preparative scale by means of photoinduced electron transfer (PET). In general, C-60(.+) reacts with various H-donors such as alcohols, aldehydes, ethers etc., under formation of 1,2-dihydro[60]fullerenes. In case of tert-butanol, propionic acid and glycol, for example, product formation is also initiated by H-abstraction from the OH group. Both time-resolved laser flash photolysis studies and ESR spectroscopic investigations clearly demonstrate the formation of C-60(.+) using PET conditions. Upon addition of H-donors such as methanol the signal of C-60(.+) is quenched as monitored both by laser flash photolysis and ESR spectroscopy. Based on these studies we assume the oxidation of C-60 followed by abstraction of hydrogen from the H-donor.
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Siedschlag C, Dunsch L, Ito O, Mattay J. [60]fullerene radical cation reactions and mechanism. In: JOURNAL OF INFORMATION RECORDING. Vol 25. GORDON BREACH SCI PUBL LTD; 2000: 265-271.
Siedschlag, C., Dunsch, L., Ito, O., & Mattay, J. (2000). [60]fullerene radical cation reactions and mechanism. JOURNAL OF INFORMATION RECORDING, 25(3-4), 265-271.
Siedschlag, C., Dunsch, L., Ito, O., and Mattay, J. (2000). “[60]fullerene radical cation reactions and mechanism” in JOURNAL OF INFORMATION RECORDING, vol. 25, (GORDON BREACH SCI PUBL LTD), 265-271.
Siedschlag, C., et al., 2000. [60]fullerene radical cation reactions and mechanism. In JOURNAL OF INFORMATION RECORDING. no.25 GORDON BREACH SCI PUBL LTD, pp. 265-271.
C. Siedschlag, et al., “[60]fullerene radical cation reactions and mechanism”, JOURNAL OF INFORMATION RECORDING, vol. 25, GORDON BREACH SCI PUBL LTD, 2000, pp.265-271.
Siedschlag, C., Dunsch, L., Ito, O., Mattay, J.: [60]fullerene radical cation reactions and mechanism. JOURNAL OF INFORMATION RECORDING. 25, p. 265-271. GORDON BREACH SCI PUBL LTD (2000).
Siedschlag, C, Dunsch, L, Ito, O, and Mattay, Jochen. “[60]fullerene radical cation reactions and mechanism”. JOURNAL OF INFORMATION RECORDING. GORDON BREACH SCI PUBL LTD, 2000.Vol. 25. 265-271.
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