A new type of calixarene: Octahydroxypyridine[4]arenes

Gerkensmeier T, Mattay J, Nather C (2001)
CHEMISTRY-A EUROPEAN JOURNAL 7(2): 465-474.

Journal Article | Published | English

No fulltext has been uploaded

Author
; ;
Abstract
A new type of calixarene has been synthesised. Like resorcinol and a number of resorcinol derivatives, 2,6-dihydroxypyridine has been proven to form cyclic tetramers in moderate yields with a number of aliphatic and two aromatic aldehydes in acidic media. The problem of the formation of configurational isomers can be reduced by increasing the reaction temperature and time. With electron-rich aromatic aldehydes, 2,6-dihydroxypyridine unexpectedly yields deep-coloured acyclic quinoid systems. The octahydroxypyridine[4]arenes may have a high potential as receptors for molecular recognition and self organisation.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Gerkensmeier T, Mattay J, Nather C. A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL. 2001;7(2):465-474.
Gerkensmeier, T., Mattay, J., & Nather, C. (2001). A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL, 7(2), 465-474.
Gerkensmeier, T., Mattay, J., and Nather, C. (2001). A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL 7, 465-474.
Gerkensmeier, T., Mattay, J., & Nather, C., 2001. A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL, 7(2), p 465-474.
T. Gerkensmeier, J. Mattay, and C. Nather, “A new type of calixarene: Octahydroxypyridine[4]arenes”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 7, 2001, pp. 465-474.
Gerkensmeier, T., Mattay, J., Nather, C.: A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL. 7, 465-474 (2001).
Gerkensmeier, T, Mattay, Jochen, and Nather, C. “A new type of calixarene: Octahydroxypyridine[4]arenes”. CHEMISTRY-A EUROPEAN JOURNAL 7.2 (2001): 465-474.
This data publication is cited in the following publications:
This publication cites the following data publications:

2 Citations in Europe PMC

Data provided by Europe PubMed Central.

Recent advances in hydrogen-bonded hexameric encapsulation complexes.
Avram L, Cohen Y, Rebek J Jr., Chem. Commun. (Camb.) 47(19), 2011
PMID: 21431233

41 References

Data provided by Europe PubMed Central.

Molecular Boxes Based on Calix[4]arene Double Rosettes
Vreekamp, Angewandte Chemie International Edition in English 35(11), 1996
Synthesis of a pyridine-containing xanthoporphinogen-type model. An entrance to heterocalixarenes
Newkome, Journal of the Chemical Society Chemical Communications (11), 1987
Hydrogen-bonded dimers of tetraurea calix[4]arenes: unambiguous proof by single crystal X-ray analysis
Mogck, Chemical Communications (22), 1996
Potentially tautomeric pyridines. Part VII. Glutaconimide and its methyl derivatives
Katritzky, Journal of the Chemical Society B Physical Organic (), 1966
Spectral and ionisation constant studies of substituted 2-hydroxypyridines (1,2-dihydro-2-oxopyridines)
Spinner, Journal of the Chemical Society B Physical Organic (), 1966
Do calix[n]arenes really exist as discrete monomers in solution? Comments based on mass spectrometry
Inokuchi, Journal of the Chemical Society Perkin Transactions 2 (4), 1996

Atkins, The Journal of Organic Chemistry 43(10), 1978
Self-Assembly of 2,8,14,20-Tetraisobutyl-5,11,17,23-tetrahydroxyresorc[4]arene
Gerkensmeier, European Journal of Organic Chemistry 1999(9), 1999
Charakterisierung von supramolekularen Wasserstoffbrücken-Aggregaten durch MALDI-TOF-Massenspektrometrie nach Markierung mit Ag+
Jolliffe, Angewandte Chemie 110(9), 1998
Aufbau durch Wasserstoffbrücken zusammengehaltener Nanostrukturen aus 15 Komponenten
Jolliffe, Angewandte Chemie 111(7), 1999
Synthese und Charakterisierung einer unimolekularen Kapsel
Brody, Angewandte Chemie 111(11), 1999
Reversibler Einschluß von Gastmolekülen in ein Calixarendimer
Hamann, Angewandte Chemie 108(12), 1996
Molekulare Kästen auf der Basis von Calix[4]aren-Doppelrosetten
Vreekamp, Angewandte Chemie 108(11), 1996
Eine Synthese von Pyridin-Derivaten
Gattermann, Berichte der deutschen chemischen Gesellschaft 49(1), 1916
Noncovalent Assembly of Functional Groups on Calix[4]Arene Molecular Boxes
Timmerman, Chemistry - A European Journal 3(11), 1997

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Sources

PMID: 11271533
PubMed | Europe PMC

Search this title in

Google Scholar