Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods

Schoeller W, Rozhenko AJB, Alijah A (2001)
JOURNAL OF ORGANOMETALLIC CHEMISTRY 617-618(1): 435-443.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The formation of coordination compounds of phosphanyl carbenes with a transition metal in a high oxidation state (Schrock type) is evaluated by density functional theory. In the Schrock type carbene complexes the transition metal-carbon bond possesses a multiple bond character. If one of the ligands at the carbene center possesses a leaving ability, e.g. as the diaminophosphenium unit, a facile distortion to a new type of an anionic metallaalkylidene donor-acceptor complex with a diaminophosphenium cation is predicted. (C) 2001 Elsevier Science B.V. All rights reserved.
Erscheinungsjahr
Zeitschriftentitel
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Band
617-618
Zeitschriftennummer
1
Seite
435-443
ISSN
PUB-ID

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Schoeller W, Rozhenko AJB, Alijah A. Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2001;617-618(1):435-443.
Schoeller, W., Rozhenko, A. J. B., & Alijah, A. (2001). Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 617-618(1), 435-443. doi:10.1016/S0022-328X(00)00647-1
Schoeller, W., Rozhenko, A. J. B., and Alijah, A. (2001). Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods. JOURNAL OF ORGANOMETALLIC CHEMISTRY 617-618, 435-443.
Schoeller, W., Rozhenko, A.J.B., & Alijah, A., 2001. Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 617-618(1), p 435-443.
W. Schoeller, A.J.B. Rozhenko, and A. Alijah, “Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods”, JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 617-618, 2001, pp. 435-443.
Schoeller, W., Rozhenko, A.J.B., Alijah, A.: Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 617-618, 435-443 (2001).
Schoeller, Wolfgang, Rozhenko, AJB, and Alijah, A. “Schrock type transition metal complex formation of push-pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 617-618.1 (2001): 435-443.