Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties

Jutzi P, Müller C, Neumann B, Stammler H-G (2001)
European Journal of Inorganic Chemistry 625(2): 180-185.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
Donor substituted carbon- and silicon-bridged zirconocene dichlorides of the type [eta (5)-C13H8-CMe2-eta (5)-C5H3(CH2CH2NR2)]ZrCl2 (R = Me (2a), Et (2b), Pr-i (2c)) and [eta (5)-C13H8-SiMe2-eta (5)-C5H3(CH2CH2NR2)]ZrCl2 (R = Me (4a), Et (4b), Pr-i (4c)) have been prepared. Activation of 2a-c and 4a-c with excess methylalumoxane results in the formation of catalytically active species for the polymerization of ethylene and propylene. (C) 2001 Elsevier Science B.V. All rights reserved.
Erscheinungsjahr
Zeitschriftentitel
European Journal of Inorganic Chemistry
Band
625
Zeitschriftennummer
2
Seite
180-185
ISSN
PUB-ID

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Jutzi P, Müller C, Neumann B, Stammler H-G. Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry. 2001;625(2):180-185.
Jutzi, P., Müller, C., Neumann, B., & Stammler, H. - G. (2001). Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry, 625(2), 180-185. doi:10.1016/S0022-328X(01)00644-1
Jutzi, P., Müller, C., Neumann, B., and Stammler, H. - G. (2001). Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry 625, 180-185.
Jutzi, P., et al., 2001. Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry, 625(2), p 180-185.
P. Jutzi, et al., “Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties”, European Journal of Inorganic Chemistry, vol. 625, 2001, pp. 180-185.
Jutzi, P., Müller, C., Neumann, B., Stammler, H.-G.: Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry. 625, 180-185 (2001).
Jutzi, Peter, Müller, Christian, Neumann, Beate, and Stammler, Hans-Georg. “Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties”. European Journal of Inorganic Chemistry 625.2 (2001): 180-185.