The reaction of giant wheel polyoxomolybdate clusters with ethanol

Bielanski A, Malecka-Lubanska A, Pozniczek J, Müller A, Krickemeyer E, Diemann E (2001)
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 49(1): 85-99.

Journal Article | Published | English

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Abstract
The conversion of ethanol at 100-280 degreesC was used in order to characterise the redox and acid centres present in Na-15{05[Mo152O457H14(H2O)(68)] .0.5[Mo154O462H14 (H2O)(70)]}.ca. 400 H2O (1). It is concluded that Mo-V/Mo-VI pairs at the external surface of the rings, of which the structure of 1 is composed, are the redox centres active in ethanol dehydrogenation to acetaldehyde. Simultaneous ethanol dehydration to diethyl ether or ethylene is a typical reaction occurring on acid centres. It is suggested that OH groups situated in (mu (3) -O)(2)O-2 tetrahedrons inside the ring structure play such role. The formation of ethane predominating at highest temperatures is attributed to secondary reactions of primary ethylene.
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Bielanski A, Malecka-Lubanska A, Pozniczek J, Müller A, Krickemeyer E, Diemann E. The reaction of giant wheel polyoxomolybdate clusters with ethanol. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY. 2001;49(1):85-99.
Bielanski, A., Malecka-Lubanska, A., Pozniczek, J., Müller, A., Krickemeyer, E., & Diemann, E. (2001). The reaction of giant wheel polyoxomolybdate clusters with ethanol. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 49(1), 85-99.
Bielanski, A., Malecka-Lubanska, A., Pozniczek, J., Müller, A., Krickemeyer, E., and Diemann, E. (2001). The reaction of giant wheel polyoxomolybdate clusters with ethanol. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 49, 85-99.
Bielanski, A., et al., 2001. The reaction of giant wheel polyoxomolybdate clusters with ethanol. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 49(1), p 85-99.
A. Bielanski, et al., “The reaction of giant wheel polyoxomolybdate clusters with ethanol”, BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, vol. 49, 2001, pp. 85-99.
Bielanski, A., Malecka-Lubanska, A., Pozniczek, J., Müller, A., Krickemeyer, E., Diemann, E.: The reaction of giant wheel polyoxomolybdate clusters with ethanol. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY. 49, 85-99 (2001).
Bielanski, A, Malecka-Lubanska, A, Pozniczek, J, Müller, Achim, Krickemeyer, Erich, and Diemann, Ekkehard. “The reaction of giant wheel polyoxomolybdate clusters with ethanol”. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 49.1 (2001): 85-99.
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