(Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent

Sole S, Gornitzka H, Schoeller W, Bourissou D, Bertrand G (2001)
SCIENCE 292(5523): 1901-1903.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Several (amino)(aryl)carbenes have been shown to be stable at room temperature in solution and in the solid state. Electroneutrality of the carbene center is ensured by the amino group, which has both pi -donor and sigma -acceptor electronic character. The aryl group remains a spectator substituent, as shown by single-crystal x-ray analysis and by its chemical behavior. Because only one electron-active substituent is needed, numerous stable carbenes will become accessible, which will open the way for new synthetic developments and applications in various fields.
Erscheinungsjahr
Zeitschriftentitel
SCIENCE
Band
292
Zeitschriftennummer
5523
Seite
1901-1903
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Sole S, Gornitzka H, Schoeller W, Bourissou D, Bertrand G. (Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent. SCIENCE. 2001;292(5523):1901-1903.
Sole, S., Gornitzka, H., Schoeller, W., Bourissou, D., & Bertrand, G. (2001). (Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent. SCIENCE, 292(5523), 1901-1903. doi:10.1126/science.292.5523.1901
Sole, S., Gornitzka, H., Schoeller, W., Bourissou, D., and Bertrand, G. (2001). (Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent. SCIENCE 292, 1901-1903.
Sole, S., et al., 2001. (Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent. SCIENCE, 292(5523), p 1901-1903.
S. Sole, et al., “(Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent”, SCIENCE, vol. 292, 2001, pp. 1901-1903.
Sole, S., Gornitzka, H., Schoeller, W., Bourissou, D., Bertrand, G.: (Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent. SCIENCE. 292, 1901-1903 (2001).
Sole, S, Gornitzka, H, Schoeller, Wolfgang, Bourissou, D, and Bertrand, G. “(Amino)(aryl)carbenes: Stable singlet carbenes featuring a spectator substituent”. SCIENCE 292.5523 (2001): 1901-1903.

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