(Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates

Müller A, Kuhlmann C, Bögge H, Schmidtmann M, Baumann M, Krickemeyer E (2001)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (9): 2271-2277.

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dThe synthesis and structural characterization of a novel series of deep-red mixed-valence (Mo-VI/Mo-V) compounds with nano-sized spherically shaped cluster anions containing 18, 40, or 54 Mo atoms, respectively, is reported: Na-10-[H4Mo18O56(CH3COO)(2)] x ca. 36 H2O x 3 CH3COOH (1), (NH4)(12)Na-12[Mo40O128] x ca. 70 H2O (2), (NH4)(12)Na-20[H-4-Mo54O168(CH3COO)(4)] x ca. 64 H2O (3), Na-32[H4Mo54O168(CH3COO)(4)] x ca. 128 H2O (4), and Na-32[H4Mo54O168(CH3COO)(4)] x ca. 98 H2O (S). Clusters 3, 4, and 5 differ in the packing of the rings in the lattice. The anions are easily formed by reduction of an acidified aqueous molybdate solution while the deliberately generated (MO2O42+)-O-V group - abundant in all clusters - has a directing influence on the formation of the preliminary building blocks. Furthermore, it is possible to control the ratio of the {Mo-2(V)} units to the Mo-VI centres by adjusting the specific concentration of the employed reducing agent.
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Müller A, Kuhlmann C, Bögge H, Schmidtmann M, Baumann M, Krickemeyer E. (Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2001;(9):2271-2277.
Müller, A., Kuhlmann, C., Bögge, H., Schmidtmann, M., Baumann, M., & Krickemeyer, E. (2001). (Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(9), 2271-2277.
Müller, A., Kuhlmann, C., Bögge, H., Schmidtmann, M., Baumann, M., and Krickemeyer, E. (2001). (Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2271-2277.
Müller, A., et al., 2001. (Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (9), p 2271-2277.
A. Müller, et al., “(Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, pp. 2271-2277.
Müller, A., Kuhlmann, C., Bögge, H., Schmidtmann, M., Baumann, M., Krickemeyer, E.: (Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2271-2277 (2001).
Müller, Achim, Kuhlmann, Christoph, Bögge, Hartmut, Schmidtmann, Marc, Baumann, M, and Krickemeyer, Erich. “(Mo2O42+)-O-v directs the formation and subsequent linking of potential building blocks under different boundary conditions: A related set of novel cyclic polyoxomolybdates”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 9 (2001): 2271-2277.
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