Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster

Müller A, Maiti R, Schmidtmann M, Bögge H, Das SK, Zhang WJ (2001)
CHEMICAL COMMUNICATIONS (20): 2126-2127.

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Abstract
The mixed valence cluster anion of the compound (NH4)(32)[(Mo110Mo28O416H6)-Mo-VI-O-V(H2O)(58)(CH3CO2)(6)]. xH(2)O 1 (x similar to 250), synthesized under one-pot conditions, contains well-defined different types of defects-missing groups compared to the complete parent {Mo-154} type cluster with full D-7d symmetry-and acetate ligand coordination; this proves that the giant-wheel type anion can be considered as an object with a variety of nanoscale structural features ("nanostructured landscape") allowing reactions at a variety of well defined centers.
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Müller A, Maiti R, Schmidtmann M, Bögge H, Das SK, Zhang WJ. Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster. CHEMICAL COMMUNICATIONS. 2001;(20):2126-2127.
Müller, A., Maiti, R., Schmidtmann, M., Bögge, H., Das, S. K., & Zhang, W. J. (2001). Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster. CHEMICAL COMMUNICATIONS(20), 2126-2127.
Müller, A., Maiti, R., Schmidtmann, M., Bögge, H., Das, S. K., and Zhang, W. J. (2001). Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster. CHEMICAL COMMUNICATIONS, 2126-2127.
Müller, A., et al., 2001. Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster. CHEMICAL COMMUNICATIONS, (20), p 2126-2127.
A. Müller, et al., “Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster”, CHEMICAL COMMUNICATIONS, 2001, pp. 2126-2127.
Müller, A., Maiti, R., Schmidtmann, M., Bögge, H., Das, S.K., Zhang, W.J.: Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster. CHEMICAL COMMUNICATIONS. 2126-2127 (2001).
Müller, Achim, Maiti, R, Schmidtmann, Marc, Bögge, Hartmut, Das, Samar K., and Zhang, WJ. “Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster”. CHEMICAL COMMUNICATIONS 20 (2001): 2126-2127.
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Inorganic chemistry goes protein size: a Mo368 nano-hedgehog initiating nanochemistry by symmetry breaking.
Muller A, Beckmann E, Bogge H, Schmidtmann M, Dress A., Angew. Chem. Int. Ed. Engl. 41(7), 2002
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