Design of molecular rectangles by using compartmental and exo-bidentate ligands

Visinescu D, Andruh M, Müller A, Schmidtmann M, Journaux Y (2002)
INORGANIC CHEMISTRY COMMUNICATIONS 5(1): 42-45.

Journal Article | Published | English

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Abstract
Molecular rectangles with different sizes can be obtained by reacting a binuclear copper(II) complex, [L(mu-OH)Cu-2](ClO4)(2) (L = the compartmental end-off ligand. 2,6-bis[N-(2-pyridylethyl)formimidoyl]-phenolato), with bis-(4-pyridyl) derivatives (4,4'-bi-pyridine, 1,2-bis(4-pyridyl)ethylene). Two tetranuclear complexes have been obtained and characterized by single-crystal X-ray diffraction: [{L(mu-OH)Cu-2}-(mu-4,4'-bipy)(2)-{Cu-2(mu-OH)L}](ClO4)(4) . 3H(2)O (1), and [{L(mu-OH)Cu-2}-(mu-bpe)(2)-{Cu-2(mu-OH)L}] (ClO4)(4) . 4H(2)O (2). Compounds 1 and 2 have been obtained also through a multicomponent self-assembly process, namely by mixing together the stoichiometric amounts of compartmental Schiff base, exo-bidentate ligand and lithium hydroxide. followed by the addition of copper(II) perchlorate. (C) 2002 Elsevier Science B.V. All rights reserved.
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Visinescu D, Andruh M, Müller A, Schmidtmann M, Journaux Y. Design of molecular rectangles by using compartmental and exo-bidentate ligands. INORGANIC CHEMISTRY COMMUNICATIONS. 2002;5(1):42-45.
Visinescu, D., Andruh, M., Müller, A., Schmidtmann, M., & Journaux, Y. (2002). Design of molecular rectangles by using compartmental and exo-bidentate ligands. INORGANIC CHEMISTRY COMMUNICATIONS, 5(1), 42-45.
Visinescu, D., Andruh, M., Müller, A., Schmidtmann, M., and Journaux, Y. (2002). Design of molecular rectangles by using compartmental and exo-bidentate ligands. INORGANIC CHEMISTRY COMMUNICATIONS 5, 42-45.
Visinescu, D., et al., 2002. Design of molecular rectangles by using compartmental and exo-bidentate ligands. INORGANIC CHEMISTRY COMMUNICATIONS, 5(1), p 42-45.
D. Visinescu, et al., “Design of molecular rectangles by using compartmental and exo-bidentate ligands”, INORGANIC CHEMISTRY COMMUNICATIONS, vol. 5, 2002, pp. 42-45.
Visinescu, D., Andruh, M., Müller, A., Schmidtmann, M., Journaux, Y.: Design of molecular rectangles by using compartmental and exo-bidentate ligands. INORGANIC CHEMISTRY COMMUNICATIONS. 5, 42-45 (2002).
Visinescu, D, Andruh, Marius, Müller, Achim, Schmidtmann, Marc, and Journaux, Yves. “Design of molecular rectangles by using compartmental and exo-bidentate ligands”. INORGANIC CHEMISTRY COMMUNICATIONS 5.1 (2002): 42-45.
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