The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n)

Althoff A, Jutzi P, Lenze N, Neumann B, Stammler A, Stammler H-G (2002)
ORGANOMETALLICS 21(14): 3018-3022.

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The reaction of 1,1'-bis(trichlorostannyl)ferrocene with trimethylgallium results in the formation of Fe(C5H4GaMe2)(2) (1), the first digallylferrocene. An X-ray crystal structure analysis of 1 reveals a polymeric structure. NMR data confirm a monomeric structure of [1(.)2 donor] in donor solvents. The reaction of 1 with phenazine results in the formation of the supramolecular polyferrocene [1(.)phenazine](n). Its rodlike structure is proven by X-ray crystallography.
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Althoff A, Jutzi P, Lenze N, Neumann B, Stammler A, Stammler H-G. The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n). ORGANOMETALLICS. 2002;21(14):3018-3022.
Althoff, A., Jutzi, P., Lenze, N., Neumann, B., Stammler, A., & Stammler, H. - G. (2002). The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n). ORGANOMETALLICS, 21(14), 3018-3022.
Althoff, A., Jutzi, P., Lenze, N., Neumann, B., Stammler, A., and Stammler, H. - G. (2002). The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n). ORGANOMETALLICS 21, 3018-3022.
Althoff, A., et al., 2002. The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n). ORGANOMETALLICS, 21(14), p 3018-3022.
A. Althoff, et al., “The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n)”, ORGANOMETALLICS, vol. 21, 2002, pp. 3018-3022.
Althoff, A., Jutzi, P., Lenze, N., Neumann, B., Stammler, A., Stammler, H.-G.: The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n). ORGANOMETALLICS. 21, 3018-3022 (2002).
Althoff, A, Jutzi, Peter, Lenze, N, Neumann, B, Stammler, A, and Stammler, Hans-Georg. “The first 1,1 '-digallylferrocene and a rodlike, polymeric donor-acceptor complex: Synthesis, properties, and structure of [Fe(eta(5)-C5H4GaMe2)(2)](n) and [Fe(eta(5)-C5H4GaMe2)(2)(C12H8N2)](n)”. ORGANOMETALLICS 21.14 (2002): 3018-3022.
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