Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes

Volkmer D, Fricke M, Agena C, Mattay J (2002)
CRYSTENGCOMM 4(52): 288-295.

Journal Article | Published | English

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Abstract
The crystal structures of rccc-5,11,17,23-tetracarboxy-4,6,10,12,16,18,22,24,-octa-O-methyl-2,8,14 , 20-tetra(n-undecyl)resorc[4]arene, 1, and its Ca salt, 2, are described. Structural data were analyzed in terms of supramolecular packing motifs of the constituent amphiphilic macrocycles. Monolayer experiments indicate that a similar packing arrangement can be predicted for monolayers of 1 spread at the air-water interface. CaCO3 (calcite) single crystals were grown underneath monolayers of 1 with highly uniform (012) orientation. This particular orientation was observed for a variety of structurally dissimilar monolayers indicating that macroscopic films properties such as average charge density or mean dipole moment have a decisive influence on templated calcite growth.
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Volkmer D, Fricke M, Agena C, Mattay J. Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes. CRYSTENGCOMM. 2002;4(52):288-295.
Volkmer, D., Fricke, M., Agena, C., & Mattay, J. (2002). Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes. CRYSTENGCOMM, 4(52), 288-295.
Volkmer, D., Fricke, M., Agena, C., and Mattay, J. (2002). Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes. CRYSTENGCOMM 4, 288-295.
Volkmer, D., et al., 2002. Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes. CRYSTENGCOMM, 4(52), p 288-295.
D. Volkmer, et al., “Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes”, CRYSTENGCOMM, vol. 4, 2002, pp. 288-295.
Volkmer, D., Fricke, M., Agena, C., Mattay, J.: Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes. CRYSTENGCOMM. 4, 288-295 (2002).
Volkmer, D, Fricke, M, Agena, C, and Mattay, Jochen. “Oriented crystallization of calcite single crystals grown underneath monolayers of tetracarboxyresorc[4]arenes”. CRYSTENGCOMM 4.52 (2002): 288-295.
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