Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives

Botar B, Bögge H, Müller A (2002)
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 50(2): 139-144.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
For the first time it was possible to introduce heterometals (V-IV) into the important [XW9O33](9-) (X=As-III, Sb-III and B-III) building block thereby offering new pathways for related chemistry. By reaction of a VOSO4.5H(2)O solution in high excess with [(SbW9O33)(2)(WO2)(4)(OH)(2)](12-) (molar ratio of 12:1) in acetic buffer solution, a compound containing the basic-type anions like [(SbW8VO33)(2)(VO)(2)(H2O)(4)(WO2)(2)](14-) which in principle could be protonated with different degrees, can be obtained. This opens new perspectives for magnetochemistry and reactivity studies of these types of compounds.
Erscheinungsjahr
Zeitschriftentitel
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY
Band
50
Zeitschriftennummer
2
Seite
139-144
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Botar B, Bögge H, Müller A. Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY. 2002;50(2):139-144.
Botar, B., Bögge, H., & Müller, A. (2002). Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 50(2), 139-144.
Botar, B., Bögge, H., and Müller, A. (2002). Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 50, 139-144.
Botar, B., Bögge, H., & Müller, A., 2002. Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 50(2), p 139-144.
B. Botar, H. Bögge, and A. Müller, “Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives”, BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, vol. 50, 2002, pp. 139-144.
Botar, B., Bögge, H., Müller, A.: Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY. 50, 139-144 (2002).
Botar, Bogdan, Bögge, Hartmut, and Müller, Achim. “Introducing heterometal centers into a [XW9O33](9-)type building block: A first step for related derivatives”. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 50.2 (2002): 139-144.